Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

FeV(O)(OH) species have long been thought to play a role in a range of enzymatic oxidations, but their characterization has remained elusive. Here, using gas-phase ion spectroscopy, the authors characterize an FeV(O)(OH) species and find that its reactivity mimics that of Rieske oxygenases.

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Autores principales:	Margarida Borrell, Erik Andris, Rafael Navrátil, Jana Roithová, Miquel Costas
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cb139decfb1c4ebcb3f29b2332f6161c
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spelling	oai:doaj.org-article:cb139decfb1c4ebcb3f29b2332f6161c2021-12-02T14:39:16ZCharacterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase10.1038/s41467-019-08668-22041-1723https://doaj.org/article/cb139decfb1c4ebcb3f29b2332f6161c2019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08668-2https://doaj.org/toc/2041-1723FeV(O)(OH) species have long been thought to play a role in a range of enzymatic oxidations, but their characterization has remained elusive. Here, using gas-phase ion spectroscopy, the authors characterize an FeV(O)(OH) species and find that its reactivity mimics that of Rieske oxygenases.Margarida BorrellErik AndrisRafael NavrátilJana RoithováMiquel CostasNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Margarida Borrell Erik Andris Rafael Navrátil Jana Roithová Miquel Costas Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
description	FeV(O)(OH) species have long been thought to play a role in a range of enzymatic oxidations, but their characterization has remained elusive. Here, using gas-phase ion spectroscopy, the authors characterize an FeV(O)(OH) species and find that its reactivity mimics that of Rieske oxygenases.
format	article
author	Margarida Borrell Erik Andris Rafael Navrátil Jana Roithová Miquel Costas
author_facet	Margarida Borrell Erik Andris Rafael Navrátil Jana Roithová Miquel Costas
author_sort	Margarida Borrell
title	Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
title_short	Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
title_full	Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
title_fullStr	Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
title_full_unstemmed	Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
title_sort	characterized cis-fev(o)(oh) intermediate mimics enzymatic oxidations in the gas phase
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/cb139decfb1c4ebcb3f29b2332f6161c
work_keys_str_mv	AT margaridaborrell characterizedcisfevoohintermediatemimicsenzymaticoxidationsinthegasphase AT erikandris characterizedcisfevoohintermediatemimicsenzymaticoxidationsinthegasphase AT rafaelnavratil characterizedcisfevoohintermediatemimicsenzymaticoxidationsinthegasphase AT janaroithova characterizedcisfevoohintermediatemimicsenzymaticoxidationsinthegasphase AT miquelcostas characterizedcisfevoohintermediatemimicsenzymaticoxidationsinthegasphase
_version_	1718390681342312448

Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

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