Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts
We demonstrated highly efficient oxygen reduction catalysts composed of uniform Pt nanoparticles on small, reduced graphene oxides (srGO). The reduced graphene oxide (rGO) size was controlled by applying ultrasonication, and the resultant srGO enabled the morphological control of the Pt nanoparticle...
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MDPI AG
2021
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oai:doaj.org-article:cb64787c548041ebafaf59743cd5937c2021-11-25T17:55:12ZSmall Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts10.3390/ijms2222123001422-00671661-6596https://doaj.org/article/cb64787c548041ebafaf59743cd5937c2021-11-01T00:00:00Zhttps://www.mdpi.com/1422-0067/22/22/12300https://doaj.org/toc/1661-6596https://doaj.org/toc/1422-0067We demonstrated highly efficient oxygen reduction catalysts composed of uniform Pt nanoparticles on small, reduced graphene oxides (srGO). The reduced graphene oxide (rGO) size was controlled by applying ultrasonication, and the resultant srGO enabled the morphological control of the Pt nanoparticles. The prepared catalysts provided efficient surface reactions and exhibited large surface areas and high metal dispersions. The resulting Pt/srGO samples exhibited excellent oxygen reduction performance and high stability over 1000 cycles of accelerated durability tests, especially the sample treated with 2 h of sonication. Detailed investigations of the structural and electrochemical properties of the resulting catalysts suggested that both the chemical functionality and electrical conductivity of these samples greatly influence their enhanced oxygen reduction efficiency.Su-Jeong BakSun-I KimSu-yeong LimTaehyo KimSe-Hun KwonDuck Hyun LeeMDPI AGarticleoxygen reduction reactionproton exchange membrane fuel cellgraphenePt catalystBiology (General)QH301-705.5ChemistryQD1-999ENInternational Journal of Molecular Sciences, Vol 22, Iss 12300, p 12300 (2021) |
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oxygen reduction reaction proton exchange membrane fuel cell graphene Pt catalyst Biology (General) QH301-705.5 Chemistry QD1-999 |
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oxygen reduction reaction proton exchange membrane fuel cell graphene Pt catalyst Biology (General) QH301-705.5 Chemistry QD1-999 Su-Jeong Bak Sun-I Kim Su-yeong Lim Taehyo Kim Se-Hun Kwon Duck Hyun Lee Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
description |
We demonstrated highly efficient oxygen reduction catalysts composed of uniform Pt nanoparticles on small, reduced graphene oxides (srGO). The reduced graphene oxide (rGO) size was controlled by applying ultrasonication, and the resultant srGO enabled the morphological control of the Pt nanoparticles. The prepared catalysts provided efficient surface reactions and exhibited large surface areas and high metal dispersions. The resulting Pt/srGO samples exhibited excellent oxygen reduction performance and high stability over 1000 cycles of accelerated durability tests, especially the sample treated with 2 h of sonication. Detailed investigations of the structural and electrochemical properties of the resulting catalysts suggested that both the chemical functionality and electrical conductivity of these samples greatly influence their enhanced oxygen reduction efficiency. |
format |
article |
author |
Su-Jeong Bak Sun-I Kim Su-yeong Lim Taehyo Kim Se-Hun Kwon Duck Hyun Lee |
author_facet |
Su-Jeong Bak Sun-I Kim Su-yeong Lim Taehyo Kim Se-Hun Kwon Duck Hyun Lee |
author_sort |
Su-Jeong Bak |
title |
Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
title_short |
Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
title_full |
Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
title_fullStr |
Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
title_full_unstemmed |
Small Reduced Graphene Oxides for Highly Efficient Oxygen Reduction Catalysts |
title_sort |
small reduced graphene oxides for highly efficient oxygen reduction catalysts |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/cb64787c548041ebafaf59743cd5937c |
work_keys_str_mv |
AT sujeongbak smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts AT sunikim smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts AT suyeonglim smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts AT taehyokim smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts AT sehunkwon smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts AT duckhyunlee smallreducedgrapheneoxidesforhighlyefficientoxygenreductioncatalysts |
_version_ |
1718411888277061632 |