Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping

Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were...

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Autores principales: Jae Ki Lee, Min-Wook Oh, Byungki Ryu, Ji Eun Lee, Bong-Seo Kim, Bok-Ki Min, Sung-Jae Joo, Hee-Woong Lee, Su-Dong Park
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Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a3
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spelling oai:doaj.org-article:cbc70153314e41f8a746ac35c10a35a32021-12-02T15:04:53ZEnhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping10.1038/s41598-017-04885-12045-2322https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a32017-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-04885-1https://doaj.org/toc/2045-2322Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were dramatically affected by Ce doping and the lattice thermal conductivity was reduced. The presence of nanostructured Ag2Te heterophases resulted in a greatly enhanced dimensionless figure of merit, ZT of 1.5 at 673 K. These findings highlight the importance of the heterophase and doping control, which determines both electrical and thermal properties.Jae Ki LeeMin-Wook OhByungki RyuJi Eun LeeBong-Seo KimBok-Ki MinSung-Jae JooHee-Woong LeeSu-Dong ParkNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Jae Ki Lee
Min-Wook Oh
Byungki Ryu
Ji Eun Lee
Bong-Seo Kim
Bok-Ki Min
Sung-Jae Joo
Hee-Woong Lee
Su-Dong Park
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
description Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were dramatically affected by Ce doping and the lattice thermal conductivity was reduced. The presence of nanostructured Ag2Te heterophases resulted in a greatly enhanced dimensionless figure of merit, ZT of 1.5 at 673 K. These findings highlight the importance of the heterophase and doping control, which determines both electrical and thermal properties.
format article
author Jae Ki Lee
Min-Wook Oh
Byungki Ryu
Ji Eun Lee
Bong-Seo Kim
Bok-Ki Min
Sung-Jae Joo
Hee-Woong Lee
Su-Dong Park
author_facet Jae Ki Lee
Min-Wook Oh
Byungki Ryu
Ji Eun Lee
Bong-Seo Kim
Bok-Ki Min
Sung-Jae Joo
Hee-Woong Lee
Su-Dong Park
author_sort Jae Ki Lee
title Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
title_short Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
title_full Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
title_fullStr Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
title_full_unstemmed Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
title_sort enhanced thermoelectric properties of agsbte2 obtained by controlling heterophases with ce doping
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a3
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