Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping
Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were...
Guardado en:
Autores principales: | , , , , , , , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2017
|
Materias: | |
Acceso en línea: | https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a3 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:cbc70153314e41f8a746ac35c10a35a3 |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:cbc70153314e41f8a746ac35c10a35a32021-12-02T15:04:53ZEnhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping10.1038/s41598-017-04885-12045-2322https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a32017-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-04885-1https://doaj.org/toc/2045-2322Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were dramatically affected by Ce doping and the lattice thermal conductivity was reduced. The presence of nanostructured Ag2Te heterophases resulted in a greatly enhanced dimensionless figure of merit, ZT of 1.5 at 673 K. These findings highlight the importance of the heterophase and doping control, which determines both electrical and thermal properties.Jae Ki LeeMin-Wook OhByungki RyuJi Eun LeeBong-Seo KimBok-Ki MinSung-Jae JooHee-Woong LeeSu-Dong ParkNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-8 (2017) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Medicine R Science Q |
spellingShingle |
Medicine R Science Q Jae Ki Lee Min-Wook Oh Byungki Ryu Ji Eun Lee Bong-Seo Kim Bok-Ki Min Sung-Jae Joo Hee-Woong Lee Su-Dong Park Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
description |
Abstract We report the enhanced thermoelectric properties of Ce-doped AgSbTe2 (AgSb1−xCexTe2) compounds. As the Ce contents increased, the proportion of heterophase Ag2Te in the AgSbTe2 gradually decreased, along with the size of the crystals. The electrical resistivity and Seebeck coefficient were dramatically affected by Ce doping and the lattice thermal conductivity was reduced. The presence of nanostructured Ag2Te heterophases resulted in a greatly enhanced dimensionless figure of merit, ZT of 1.5 at 673 K. These findings highlight the importance of the heterophase and doping control, which determines both electrical and thermal properties. |
format |
article |
author |
Jae Ki Lee Min-Wook Oh Byungki Ryu Ji Eun Lee Bong-Seo Kim Bok-Ki Min Sung-Jae Joo Hee-Woong Lee Su-Dong Park |
author_facet |
Jae Ki Lee Min-Wook Oh Byungki Ryu Ji Eun Lee Bong-Seo Kim Bok-Ki Min Sung-Jae Joo Hee-Woong Lee Su-Dong Park |
author_sort |
Jae Ki Lee |
title |
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
title_short |
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
title_full |
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
title_fullStr |
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
title_full_unstemmed |
Enhanced thermoelectric properties of AgSbTe2 obtained by controlling heterophases with Ce doping |
title_sort |
enhanced thermoelectric properties of agsbte2 obtained by controlling heterophases with ce doping |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/cbc70153314e41f8a746ac35c10a35a3 |
work_keys_str_mv |
AT jaekilee enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT minwookoh enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT byungkiryu enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT jieunlee enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT bongseokim enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT bokkimin enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT sungjaejoo enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT heewoonglee enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping AT sudongpark enhancedthermoelectricpropertiesofagsbte2obtainedbycontrollingheterophaseswithcedoping |
_version_ |
1718389043643809792 |