Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy

Bloch–Siegert shifts prevent the accurate observation of resonance frequencies in NMR experiments. Here the authors present a method for homonuclear decoupling that avoids inducing Bloch–Siegert shifts and improves the sensitivity and resolution of HNCA experiments.

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Autores principales:	Paul W. Coote, Scott A. Robson, Abhinav Dubey, Andras Boeszoermenyi, Mengxia Zhao, Gerhard Wagner, Haribabu Arthanari
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cbceedd19fe04e49a3cca526a7eddfc5
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spelling	oai:doaj.org-article:cbceedd19fe04e49a3cca526a7eddfc52021-12-02T17:33:00ZOptimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy10.1038/s41467-018-05400-42041-1723https://doaj.org/article/cbceedd19fe04e49a3cca526a7eddfc52018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05400-4https://doaj.org/toc/2041-1723Bloch–Siegert shifts prevent the accurate observation of resonance frequencies in NMR experiments. Here the authors present a method for homonuclear decoupling that avoids inducing Bloch–Siegert shifts and improves the sensitivity and resolution of HNCA experiments.Paul W. CooteScott A. RobsonAbhinav DubeyAndras BoeszoermenyiMengxia ZhaoGerhard WagnerHaribabu ArthanariNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Paul W. Coote Scott A. Robson Abhinav Dubey Andras Boeszoermenyi Mengxia Zhao Gerhard Wagner Haribabu Arthanari Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
description	Bloch–Siegert shifts prevent the accurate observation of resonance frequencies in NMR experiments. Here the authors present a method for homonuclear decoupling that avoids inducing Bloch–Siegert shifts and improves the sensitivity and resolution of HNCA experiments.
format	article
author	Paul W. Coote Scott A. Robson Abhinav Dubey Andras Boeszoermenyi Mengxia Zhao Gerhard Wagner Haribabu Arthanari
author_facet	Paul W. Coote Scott A. Robson Abhinav Dubey Andras Boeszoermenyi Mengxia Zhao Gerhard Wagner Haribabu Arthanari
author_sort	Paul W. Coote
title	Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
title_short	Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
title_full	Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
title_fullStr	Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
title_full_unstemmed	Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy
title_sort	optimal control theory enables homonuclear decoupling without bloch–siegert shifts in nmr spectroscopy
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/cbceedd19fe04e49a3cca526a7eddfc5
work_keys_str_mv	AT paulwcoote optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT scottarobson optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT abhinavdubey optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT andrasboeszoermenyi optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT mengxiazhao optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT gerhardwagner optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy AT haribabuarthanari optimalcontroltheoryenableshomonucleardecouplingwithoutblochsiegertshiftsinnmrspectroscopy
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Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy

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