Identifying the missing link in catalyst transfer polymerization

The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polyc...

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Autores principales: Weiying He, Brian O. Patrick, Pierre Kennepohl
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b
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Sumario:The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polycondensation.