Identifying the missing link in catalyst transfer polymerization
The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polyc...
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Nature Portfolio
2018
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oai:doaj.org-article:cc07578f73b6478b9c79b08c38c3eb8b2021-12-02T14:40:05ZIdentifying the missing link in catalyst transfer polymerization10.1038/s41467-018-06324-92041-1723https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b2018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06324-9https://doaj.org/toc/2041-1723The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polycondensation.Weiying HeBrian O. PatrickPierre KennepohlNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018) |
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Science Q Weiying He Brian O. Patrick Pierre Kennepohl Identifying the missing link in catalyst transfer polymerization |
description |
The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polycondensation. |
format |
article |
author |
Weiying He Brian O. Patrick Pierre Kennepohl |
author_facet |
Weiying He Brian O. Patrick Pierre Kennepohl |
author_sort |
Weiying He |
title |
Identifying the missing link in catalyst transfer polymerization |
title_short |
Identifying the missing link in catalyst transfer polymerization |
title_full |
Identifying the missing link in catalyst transfer polymerization |
title_fullStr |
Identifying the missing link in catalyst transfer polymerization |
title_full_unstemmed |
Identifying the missing link in catalyst transfer polymerization |
title_sort |
identifying the missing link in catalyst transfer polymerization |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b |
work_keys_str_mv |
AT weiyinghe identifyingthemissinglinkincatalysttransferpolymerization AT brianopatrick identifyingthemissinglinkincatalysttransferpolymerization AT pierrekennepohl identifyingthemissinglinkincatalysttransferpolymerization |
_version_ |
1718390442478796800 |