Identifying the missing link in catalyst transfer polymerization

The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polyc...

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Autores principales: Weiying He, Brian O. Patrick, Pierre Kennepohl
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b
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spelling oai:doaj.org-article:cc07578f73b6478b9c79b08c38c3eb8b2021-12-02T14:40:05ZIdentifying the missing link in catalyst transfer polymerization10.1038/s41467-018-06324-92041-1723https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b2018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06324-9https://doaj.org/toc/2041-1723The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polycondensation.Weiying HeBrian O. PatrickPierre KennepohlNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Weiying He
Brian O. Patrick
Pierre Kennepohl
Identifying the missing link in catalyst transfer polymerization
description The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polycondensation.
format article
author Weiying He
Brian O. Patrick
Pierre Kennepohl
author_facet Weiying He
Brian O. Patrick
Pierre Kennepohl
author_sort Weiying He
title Identifying the missing link in catalyst transfer polymerization
title_short Identifying the missing link in catalyst transfer polymerization
title_full Identifying the missing link in catalyst transfer polymerization
title_fullStr Identifying the missing link in catalyst transfer polymerization
title_full_unstemmed Identifying the missing link in catalyst transfer polymerization
title_sort identifying the missing link in catalyst transfer polymerization
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/cc07578f73b6478b9c79b08c38c3eb8b
work_keys_str_mv AT weiyinghe identifyingthemissinglinkincatalysttransferpolymerization
AT brianopatrick identifyingthemissinglinkincatalysttransferpolymerization
AT pierrekennepohl identifyingthemissinglinkincatalysttransferpolymerization
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