Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the developm...
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AIDIC Servizi S.r.l.
2021
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oai:doaj.org-article:cc5a63a1c6354470b2dca86404fd608c2021-11-15T21:48:39ZPolymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium10.3303/CET21880482283-9216https://doaj.org/article/cc5a63a1c6354470b2dca86404fd608c2021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/11841https://doaj.org/toc/2283-9216In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the development of technologies for the direct conversion of plant polysaccharides, primarily cellulose, into aldonic and aldaric acids, which are widely used in chemical synthesis and various industries. It was shown that the use of Pt-containing catalytic systems based on a polymer matrix of hypercrosslinked polystyrene in the process of hydrolytic oxidation of cellobiose to gluconic and glucaric acids is promising. The yield of gluconic and glucaric acids reaches 21.6 and 63.4%, respectively.Oleg V. ManaenkovOlga V. KislitsaEkaterina A. RatkevichYuriy Yu. KosivtsovAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021) |
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Chemical engineering TP155-156 Computer engineering. Computer hardware TK7885-7895 |
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Chemical engineering TP155-156 Computer engineering. Computer hardware TK7885-7895 Oleg V. Manaenkov Olga V. Kislitsa Ekaterina A. Ratkevich Yuriy Yu. Kosivtsov Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
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In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the development of technologies for the direct conversion of plant polysaccharides, primarily cellulose, into aldonic and aldaric acids, which are widely used in chemical synthesis and various industries. It was shown that the use of Pt-containing catalytic systems based on a polymer matrix of hypercrosslinked polystyrene in the process of hydrolytic oxidation of cellobiose to gluconic and glucaric acids is promising. The yield of gluconic and glucaric acids reaches 21.6 and 63.4%, respectively. |
format |
article |
author |
Oleg V. Manaenkov Olga V. Kislitsa Ekaterina A. Ratkevich Yuriy Yu. Kosivtsov |
author_facet |
Oleg V. Manaenkov Olga V. Kislitsa Ekaterina A. Ratkevich Yuriy Yu. Kosivtsov |
author_sort |
Oleg V. Manaenkov |
title |
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
title_short |
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
title_full |
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
title_fullStr |
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
title_full_unstemmed |
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium |
title_sort |
polymeric catalysts for oxidation of cellobiose into gluconic acid in aqueous medium |
publisher |
AIDIC Servizi S.r.l. |
publishDate |
2021 |
url |
https://doaj.org/article/cc5a63a1c6354470b2dca86404fd608c |
work_keys_str_mv |
AT olegvmanaenkov polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium AT olgavkislitsa polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium AT ekaterinaaratkevich polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium AT yuriyyukosivtsov polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium |
_version_ |
1718426813203480576 |