Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium

In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the developm...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Oleg V. Manaenkov, Olga V. Kislitsa, Ekaterina A. Ratkevich, Yuriy Yu. Kosivtsov
Formato: article
Lenguaje:EN
Publicado: AIDIC Servizi S.r.l. 2021
Materias:
Acceso en línea:https://doaj.org/article/cc5a63a1c6354470b2dca86404fd608c
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:cc5a63a1c6354470b2dca86404fd608c
record_format dspace
spelling oai:doaj.org-article:cc5a63a1c6354470b2dca86404fd608c2021-11-15T21:48:39ZPolymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium10.3303/CET21880482283-9216https://doaj.org/article/cc5a63a1c6354470b2dca86404fd608c2021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/11841https://doaj.org/toc/2283-9216In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the development of technologies for the direct conversion of plant polysaccharides, primarily cellulose, into aldonic and aldaric acids, which are widely used in chemical synthesis and various industries. It was shown that the use of Pt-containing catalytic systems based on a polymer matrix of hypercrosslinked polystyrene in the process of hydrolytic oxidation of cellobiose to gluconic and glucaric acids is promising. The yield of gluconic and glucaric acids reaches 21.6 and 63.4%, respectively.Oleg V. ManaenkovOlga V. KislitsaEkaterina A. RatkevichYuriy Yu. KosivtsovAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
spellingShingle Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
Oleg V. Manaenkov
Olga V. Kislitsa
Ekaterina A. Ratkevich
Yuriy Yu. Kosivtsov
Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
description In this work, a polymer heterogeneous Pt-containing catalyst based on a mesoporous matrix of hypercrosslinked polystyrene (HPS) is proposed for the process of hydrolytic oxidation of cellobiose. Studies of the processes of hydrolytic oxidation of disaccharides are the first step towards the development of technologies for the direct conversion of plant polysaccharides, primarily cellulose, into aldonic and aldaric acids, which are widely used in chemical synthesis and various industries. It was shown that the use of Pt-containing catalytic systems based on a polymer matrix of hypercrosslinked polystyrene in the process of hydrolytic oxidation of cellobiose to gluconic and glucaric acids is promising. The yield of gluconic and glucaric acids reaches 21.6 and 63.4%, respectively.
format article
author Oleg V. Manaenkov
Olga V. Kislitsa
Ekaterina A. Ratkevich
Yuriy Yu. Kosivtsov
author_facet Oleg V. Manaenkov
Olga V. Kislitsa
Ekaterina A. Ratkevich
Yuriy Yu. Kosivtsov
author_sort Oleg V. Manaenkov
title Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
title_short Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
title_full Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
title_fullStr Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
title_full_unstemmed Polymeric Catalysts for Oxidation of Cellobiose into Gluconic Acid in Aqueous Medium
title_sort polymeric catalysts for oxidation of cellobiose into gluconic acid in aqueous medium
publisher AIDIC Servizi S.r.l.
publishDate 2021
url https://doaj.org/article/cc5a63a1c6354470b2dca86404fd608c
work_keys_str_mv AT olegvmanaenkov polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium
AT olgavkislitsa polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium
AT ekaterinaaratkevich polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium
AT yuriyyukosivtsov polymericcatalystsforoxidationofcellobioseintogluconicacidinaqueousmedium
_version_ 1718426813203480576