Reversible chromism of spiropyran in the cavity of a flexible coordination cage

Under confinement, molecular switches lose the conformational freedom often needed to isomerize. Here, the authors show that a flexible coordination cage can adapt its shape to guide the photoisomerization of encapsulated spiropyrans, rendering them reversibly photochromic even within the confines o...

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Autores principales:	Dipak Samanta, Daria Galaktionova, Julius Gemen, Linda J. W. Shimon, Yael Diskin-Posner, Liat Avram, Petr Král, Rafal Klajn
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cc6ed080eab8454589aa678da774b858
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spelling	oai:doaj.org-article:cc6ed080eab8454589aa678da774b8582021-12-02T14:40:05ZReversible chromism of spiropyran in the cavity of a flexible coordination cage10.1038/s41467-017-02715-62041-1723https://doaj.org/article/cc6ed080eab8454589aa678da774b8582018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02715-6https://doaj.org/toc/2041-1723Under confinement, molecular switches lose the conformational freedom often needed to isomerize. Here, the authors show that a flexible coordination cage can adapt its shape to guide the photoisomerization of encapsulated spiropyrans, rendering them reversibly photochromic even within the confines of the cavity.Dipak SamantaDaria GalaktionovaJulius GemenLinda J. W. ShimonYael Diskin-PosnerLiat AvramPetr KrálRafal KlajnNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dipak Samanta Daria Galaktionova Julius Gemen Linda J. W. Shimon Yael Diskin-Posner Liat Avram Petr Král Rafal Klajn Reversible chromism of spiropyran in the cavity of a flexible coordination cage
description	Under confinement, molecular switches lose the conformational freedom often needed to isomerize. Here, the authors show that a flexible coordination cage can adapt its shape to guide the photoisomerization of encapsulated spiropyrans, rendering them reversibly photochromic even within the confines of the cavity.
format	article
author	Dipak Samanta Daria Galaktionova Julius Gemen Linda J. W. Shimon Yael Diskin-Posner Liat Avram Petr Král Rafal Klajn
author_facet	Dipak Samanta Daria Galaktionova Julius Gemen Linda J. W. Shimon Yael Diskin-Posner Liat Avram Petr Král Rafal Klajn
author_sort	Dipak Samanta
title	Reversible chromism of spiropyran in the cavity of a flexible coordination cage
title_short	Reversible chromism of spiropyran in the cavity of a flexible coordination cage
title_full	Reversible chromism of spiropyran in the cavity of a flexible coordination cage
title_fullStr	Reversible chromism of spiropyran in the cavity of a flexible coordination cage
title_full_unstemmed	Reversible chromism of spiropyran in the cavity of a flexible coordination cage
title_sort	reversible chromism of spiropyran in the cavity of a flexible coordination cage
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/cc6ed080eab8454589aa678da774b858
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Reversible chromism of spiropyran in the cavity of a flexible coordination cage

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