Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature

Transamidation reactions usually require transition metal catalysts and/or harsh conditions. Here, the authors show a general and operationally-simple protocol for the transamidation of amides and amidation of esters by highly selective acyl cleavage with non-nucleophilic amines under mild condition...

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Autores principales:	Guangchen Li, Michal Szostak
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cc76dc0e7b4347d29b67230c62c50468
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spelling	oai:doaj.org-article:cc76dc0e7b4347d29b67230c62c504682021-12-02T15:33:37ZHighly selective transition-metal-free transamidation of amides and amidation of esters at room temperature10.1038/s41467-018-06623-12041-1723https://doaj.org/article/cc76dc0e7b4347d29b67230c62c504682018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06623-1https://doaj.org/toc/2041-1723Transamidation reactions usually require transition metal catalysts and/or harsh conditions. Here, the authors show a general and operationally-simple protocol for the transamidation of amides and amidation of esters by highly selective acyl cleavage with non-nucleophilic amines under mild conditions.Guangchen LiMichal SzostakNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Guangchen Li Michal Szostak Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
description	Transamidation reactions usually require transition metal catalysts and/or harsh conditions. Here, the authors show a general and operationally-simple protocol for the transamidation of amides and amidation of esters by highly selective acyl cleavage with non-nucleophilic amines under mild conditions.
format	article
author	Guangchen Li Michal Szostak
author_facet	Guangchen Li Michal Szostak
author_sort	Guangchen Li
title	Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
title_short	Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
title_full	Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
title_fullStr	Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
title_full_unstemmed	Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
title_sort	highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/cc76dc0e7b4347d29b67230c62c50468
work_keys_str_mv	AT guangchenli highlyselectivetransitionmetalfreetransamidationofamidesandamidationofestersatroomtemperature AT michalszostak highlyselectivetransitionmetalfreetransamidationofamidesandamidationofestersatroomtemperature
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Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature

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