Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation

Methods to access atropisomers bearing silanol groups are of value in organic synthesis. Here, the authors report a rhodium-catalyzed torsional strain-promoted asymmetric ring-opening reaction for the synthesis of α-silyl biaryl atropisomers.

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Detalles Bibliográficos
Autores principales: Jia Feng, Xiufen Bi, Xiaoping Xue, Na Li, Lei Shi, Zhenhua Gu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/cd6baec89afc4e6f95a8725a449ce114
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Sumario:Methods to access atropisomers bearing silanol groups are of value in organic synthesis. Here, the authors report a rhodium-catalyzed torsional strain-promoted asymmetric ring-opening reaction for the synthesis of α-silyl biaryl atropisomers.