Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation

Methods to access atropisomers bearing silanol groups are of value in organic synthesis. Here, the authors report a rhodium-catalyzed torsional strain-promoted asymmetric ring-opening reaction for the synthesis of α-silyl biaryl atropisomers.

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Autores principales:	Jia Feng, Xiufen Bi, Xiaoping Xue, Na Li, Lei Shi, Zhenhua Gu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cd6baec89afc4e6f95a8725a449ce114
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spelling	oai:doaj.org-article:cd6baec89afc4e6f95a8725a449ce1142021-12-02T14:55:09ZCatalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation10.1038/s41467-020-18273-32041-1723https://doaj.org/article/cd6baec89afc4e6f95a8725a449ce1142020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18273-3https://doaj.org/toc/2041-1723Methods to access atropisomers bearing silanol groups are of value in organic synthesis. Here, the authors report a rhodium-catalyzed torsional strain-promoted asymmetric ring-opening reaction for the synthesis of α-silyl biaryl atropisomers.Jia FengXiufen BiXiaoping XueNa LiLei ShiZhenhua GuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-12 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jia Feng Xiufen Bi Xiaoping Xue Na Li Lei Shi Zhenhua Gu Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
description	Methods to access atropisomers bearing silanol groups are of value in organic synthesis. Here, the authors report a rhodium-catalyzed torsional strain-promoted asymmetric ring-opening reaction for the synthesis of α-silyl biaryl atropisomers.
format	article
author	Jia Feng Xiufen Bi Xiaoping Xue Na Li Lei Shi Zhenhua Gu
author_facet	Jia Feng Xiufen Bi Xiaoping Xue Na Li Lei Shi Zhenhua Gu
author_sort	Jia Feng
title	Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
title_short	Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
title_full	Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
title_fullStr	Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
title_full_unstemmed	Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation
title_sort	catalytic asymmetric c–si bond activation via torsional strain-promoted rh-catalyzed aryl-narasaka acylation
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/cd6baec89afc4e6f95a8725a449ce114
work_keys_str_mv	AT jiafeng catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation AT xiufenbi catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation AT xiaopingxue catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation AT nali catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation AT leishi catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation AT zhenhuagu catalyticasymmetriccsibondactivationviatorsionalstrainpromotedrhcatalyzedarylnarasakaacylation
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Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation

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