Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells
Fine controlling chemical reactions over transition metal catalysts in living systems like enzymes remains a challenge. Here, the authors develop a versatile light-controlled bioorthogonal catalyst by modifying macroporous silica-Pd0 with supramolecular complex of azobenzene and β-cyclodextrin.
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Nature Portfolio
2018
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oai:doaj.org-article:cdc6ad1888b14152a906271e731bd0962021-12-02T17:32:17ZDesigned heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells10.1038/s41467-018-03617-x2041-1723https://doaj.org/article/cdc6ad1888b14152a906271e731bd0962018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03617-xhttps://doaj.org/toc/2041-1723Fine controlling chemical reactions over transition metal catalysts in living systems like enzymes remains a challenge. Here, the authors develop a versatile light-controlled bioorthogonal catalyst by modifying macroporous silica-Pd0 with supramolecular complex of azobenzene and β-cyclodextrin.Faming WangYan ZhangZhi DuJinsong RenXiaogang QuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018) |
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Science Q Faming Wang Yan Zhang Zhi Du Jinsong Ren Xiaogang Qu Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
description |
Fine controlling chemical reactions over transition metal catalysts in living systems like enzymes remains a challenge. Here, the authors develop a versatile light-controlled bioorthogonal catalyst by modifying macroporous silica-Pd0 with supramolecular complex of azobenzene and β-cyclodextrin. |
format |
article |
author |
Faming Wang Yan Zhang Zhi Du Jinsong Ren Xiaogang Qu |
author_facet |
Faming Wang Yan Zhang Zhi Du Jinsong Ren Xiaogang Qu |
author_sort |
Faming Wang |
title |
Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
title_short |
Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
title_full |
Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
title_fullStr |
Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
title_full_unstemmed |
Designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
title_sort |
designed heterogeneous palladium catalysts for reversible light-controlled bioorthogonal catalysis in living cells |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/cdc6ad1888b14152a906271e731bd096 |
work_keys_str_mv |
AT famingwang designedheterogeneouspalladiumcatalystsforreversiblelightcontrolledbioorthogonalcatalysisinlivingcells AT yanzhang designedheterogeneouspalladiumcatalystsforreversiblelightcontrolledbioorthogonalcatalysisinlivingcells AT zhidu designedheterogeneouspalladiumcatalystsforreversiblelightcontrolledbioorthogonalcatalysisinlivingcells AT jinsongren designedheterogeneouspalladiumcatalystsforreversiblelightcontrolledbioorthogonalcatalysisinlivingcells AT xiaogangqu designedheterogeneouspalladiumcatalystsforreversiblelightcontrolledbioorthogonalcatalysisinlivingcells |
_version_ |
1718380335812575232 |