Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel

The catalytic activity of Co and Pd loaded on mordenite (MOR) was evaluated in the hydrotreatment of cashew nut shell liquid (CNSL) into biofuel. Metals were loaded into MOR as support via wet impregnation process. The Co content was varied as 2, 4, and 6 wt.% to produce Co(1)/MOR, Co(2)/MOR, Co(3)/...

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Autores principales:	Maya Tri Hapsari, Wega Trisunaryanti, Iip Izul Falah, Media Laila Permata
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2020
Materias:	cobalt cnsl mordenite palladium Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/cdf601304d864cada2303affa39ee7ec
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spelling	oai:doaj.org-article:cdf601304d864cada2303affa39ee7ec2021-12-02T11:11:15ZCoating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel1411-94202460-157810.22146/ijc.48633https://doaj.org/article/cdf601304d864cada2303affa39ee7ec2020-07-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/48633https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The catalytic activity of Co and Pd loaded on mordenite (MOR) was evaluated in the hydrotreatment of cashew nut shell liquid (CNSL) into biofuel. Metals were loaded into MOR as support via wet impregnation process. The Co content was varied as 2, 4, and 6 wt.% to produce Co(1)/MOR, Co(2)/MOR, Co(3)/MOR catalysts. The micro-mesoporous structure of the catalyst was confirmed by XRD, SEM, TEM, FTIR, and N2 adsorption-desorption measurement. AAS were used to analyze the amount of metal that is successfully loaded in the catalysts. Hydrotreating of the CNSL was conducted in a semi-batch reactor at 450 °C with hydrogen flow (20 mL/min) for 2 h. The liquid product was analyzed using GC-MS. The activity of Co/MOR was compared with the activity of Pd/MOR as a noble metal. The result of the hydrotreatment process showed a decrease of liquid product in the sequence of Co(3)/MOR > Co(2)/MOR > Pd/MOR > Co(1)/MOR > MOR. The Co(3)/MOR catalyst exhibited the highest conversion of liquid hydrocarbon than the others (61.8 wt.%), comprising predominantly by gasoline compounds with over 25.21 wt.% conversion.Maya Tri HapsariWega TrisunaryantiIip Izul FalahMedia Laila PermataDepartment of Chemistry, Universitas Gadjah MadaarticlecobaltcnslmordenitepalladiumChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 20, Iss 5, Pp 1092-1100 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	cobalt cnsl mordenite palladium Chemistry QD1-999
spellingShingle	cobalt cnsl mordenite palladium Chemistry QD1-999 Maya Tri Hapsari Wega Trisunaryanti Iip Izul Falah Media Laila Permata Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
description	The catalytic activity of Co and Pd loaded on mordenite (MOR) was evaluated in the hydrotreatment of cashew nut shell liquid (CNSL) into biofuel. Metals were loaded into MOR as support via wet impregnation process. The Co content was varied as 2, 4, and 6 wt.% to produce Co(1)/MOR, Co(2)/MOR, Co(3)/MOR catalysts. The micro-mesoporous structure of the catalyst was confirmed by XRD, SEM, TEM, FTIR, and N2 adsorption-desorption measurement. AAS were used to analyze the amount of metal that is successfully loaded in the catalysts. Hydrotreating of the CNSL was conducted in a semi-batch reactor at 450 °C with hydrogen flow (20 mL/min) for 2 h. The liquid product was analyzed using GC-MS. The activity of Co/MOR was compared with the activity of Pd/MOR as a noble metal. The result of the hydrotreatment process showed a decrease of liquid product in the sequence of Co(3)/MOR > Co(2)/MOR > Pd/MOR > Co(1)/MOR > MOR. The Co(3)/MOR catalyst exhibited the highest conversion of liquid hydrocarbon than the others (61.8 wt.%), comprising predominantly by gasoline compounds with over 25.21 wt.% conversion.
format	article
author	Maya Tri Hapsari Wega Trisunaryanti Iip Izul Falah Media Laila Permata
author_facet	Maya Tri Hapsari Wega Trisunaryanti Iip Izul Falah Media Laila Permata
author_sort	Maya Tri Hapsari
title	Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
title_short	Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
title_full	Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
title_fullStr	Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
title_full_unstemmed	Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel
title_sort	coating of pd and co on mordenite for a catalyst of hydrotreating of cashew nut shell liquid into biofuel
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2020
url	https://doaj.org/article/cdf601304d864cada2303affa39ee7ec
work_keys_str_mv	AT mayatrihapsari coatingofpdandcoonmordeniteforacatalystofhydrotreatingofcashewnutshellliquidintobiofuel AT wegatrisunaryanti coatingofpdandcoonmordeniteforacatalystofhydrotreatingofcashewnutshellliquidintobiofuel AT iipizulfalah coatingofpdandcoonmordeniteforacatalystofhydrotreatingofcashewnutshellliquidintobiofuel AT medialailapermata coatingofpdandcoonmordeniteforacatalystofhydrotreatingofcashewnutshellliquidintobiofuel
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Coating of Pd and Co on Mordenite for a Catalyst of Hydrotreating of Cashew Nut Shell Liquid into Biofuel

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