Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications

Zeolitic imidazolate frameworks (ZIFs) are interesting materials for use in several aspects: energy storage material, gas sensing, and photocatalysis. The thermal stability and pyrolysis process are crucial in determining the active phase of the material. A deep understanding of the pyrolysis mechan...

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Autores principales:	Moustafa Ahmed, Yas M Al-Hadeethi, Ahmed Alshahrie, Arwa T Kutbee, Essam R. Shaaban, Ahmed F. Al-Hossainy
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	Zn<sub>x</sub>Co<sub>1-x</sub>-ZIF-8 metal–organic framework photocatalyst TG DSC XRD DFT Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/ce3412b4d0c341248201e342045f8d93
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spelling	oai:doaj.org-article:ce3412b4d0c341248201e342045f8d932021-11-25T18:49:46ZThermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications10.3390/polym132240512073-4360https://doaj.org/article/ce3412b4d0c341248201e342045f8d932021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/4051https://doaj.org/toc/2073-4360Zeolitic imidazolate frameworks (ZIFs) are interesting materials for use in several aspects: energy storage material, gas sensing, and photocatalysis. The thermal stability and pyrolysis process are crucial in determining the active phase of the material. A deep understanding of the pyrolysis mechanism is in demand. Therefore, the thermodynamics and combustion process with different heating rates was examined, and the kinetic parameters were computed employing thermogravimetric tests. Based on the TG analysis of combustion, pyrolysis moves to the high-temperature region with an increase in heating rate. The decomposition process can be separated into the dehydration (300–503 K) and the pyrolysis reaction (703–1100 K). Three points of the decomposition process are performed by dynamical analysis owing to shifts of slopes, but the combustion process has only one stage. The Zeolitic imidazolate framework’s structure properties were examined using TDDFT-DFT/DMOl<sup>3</sup> simulation techniques. Dynamical parameters, for instance, the possible mechanism, the pre-exponential factor, and the apparent activation energy are obtained through comparison using the Kissinger formula. The thermodynamics analysis of the Zn<sub>1-x</sub>Co<sub>x</sub>-ZIF-8 materials is an effective way to explore the temperature influence on the process of pyrolysis, which can benefit several environment purifications, photocatalyst, and recent applications.Moustafa AhmedYas M Al-HadeethiAhmed AlshahrieArwa T KutbeeEssam R. ShaabanAhmed F. Al-HossainyMDPI AGarticleZn<sub>x</sub>Co<sub>1-x</sub>-ZIF-8 metal–organic frameworkphotocatalystTGDSCXRDDFTOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 4051, p 4051 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Zn<sub>x</sub>Co<sub>1-x</sub>-ZIF-8 metal–organic framework photocatalyst TG DSC XRD DFT Organic chemistry QD241-441
spellingShingle	Zn<sub>x</sub>Co<sub>1-x</sub>-ZIF-8 metal–organic framework photocatalyst TG DSC XRD DFT Organic chemistry QD241-441 Moustafa Ahmed Yas M Al-Hadeethi Ahmed Alshahrie Arwa T Kutbee Essam R. Shaaban Ahmed F. Al-Hossainy Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
description	Zeolitic imidazolate frameworks (ZIFs) are interesting materials for use in several aspects: energy storage material, gas sensing, and photocatalysis. The thermal stability and pyrolysis process are crucial in determining the active phase of the material. A deep understanding of the pyrolysis mechanism is in demand. Therefore, the thermodynamics and combustion process with different heating rates was examined, and the kinetic parameters were computed employing thermogravimetric tests. Based on the TG analysis of combustion, pyrolysis moves to the high-temperature region with an increase in heating rate. The decomposition process can be separated into the dehydration (300–503 K) and the pyrolysis reaction (703–1100 K). Three points of the decomposition process are performed by dynamical analysis owing to shifts of slopes, but the combustion process has only one stage. The Zeolitic imidazolate framework’s structure properties were examined using TDDFT-DFT/DMOl<sup>3</sup> simulation techniques. Dynamical parameters, for instance, the possible mechanism, the pre-exponential factor, and the apparent activation energy are obtained through comparison using the Kissinger formula. The thermodynamics analysis of the Zn<sub>1-x</sub>Co<sub>x</sub>-ZIF-8 materials is an effective way to explore the temperature influence on the process of pyrolysis, which can benefit several environment purifications, photocatalyst, and recent applications.
format	article
author	Moustafa Ahmed Yas M Al-Hadeethi Ahmed Alshahrie Arwa T Kutbee Essam R. Shaaban Ahmed F. Al-Hossainy
author_facet	Moustafa Ahmed Yas M Al-Hadeethi Ahmed Alshahrie Arwa T Kutbee Essam R. Shaaban Ahmed F. Al-Hossainy
author_sort	Moustafa Ahmed
title	Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
title_short	Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
title_full	Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
title_fullStr	Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
title_full_unstemmed	Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications
title_sort	thermal analysis of a metal–organic framework znxco<sub>1-x</sub>-zif-8 for recent applications
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/ce3412b4d0c341248201e342045f8d93
work_keys_str_mv	AT moustafaahmed thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications AT yasmalhadeethi thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications AT ahmedalshahrie thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications AT arwatkutbee thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications AT essamrshaaban thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications AT ahmedfalhossainy thermalanalysisofametalorganicframeworkznxcosub1xsubzif8forrecentapplications
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Thermal Analysis of a Metal–Organic Framework ZnxCo<sub>1-X</sub>-ZIF-8 for Recent Applications

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