On-surface light-induced generation of higher acenes and elucidation of their open-shell character

The synthesis of large acenes via traditional solution-chemistry routes is hindered by their poor solubility and high reactivity under ambient conditions. Here, the authors demonstrate the on-surface formation of large acenes, via visible-light-induced photo-dissociation of α-bisdiketone molecular p...

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Autores principales:	José I. Urgel, Shantanu Mishra, Hironobu Hayashi, Jan Wilhelm, Carlo A. Pignedoli, Marco Di Giovannantonio, Roland Widmer, Masataka Yamashita, Nao Hieda, Pascal Ruffieux, Hiroko Yamada, Roman Fasel
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ce348f8f37504e2e98e3aa6b2c2e0184
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spelling	oai:doaj.org-article:ce348f8f37504e2e98e3aa6b2c2e01842021-12-02T15:36:18ZOn-surface light-induced generation of higher acenes and elucidation of their open-shell character10.1038/s41467-019-08650-y2041-1723https://doaj.org/article/ce348f8f37504e2e98e3aa6b2c2e01842019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08650-yhttps://doaj.org/toc/2041-1723The synthesis of large acenes via traditional solution-chemistry routes is hindered by their poor solubility and high reactivity under ambient conditions. Here, the authors demonstrate the on-surface formation of large acenes, via visible-light-induced photo-dissociation of α-bisdiketone molecular precursors on an Au(111) substrate.José I. UrgelShantanu MishraHironobu HayashiJan WilhelmCarlo A. PignedoliMarco Di GiovannantonioRoland WidmerMasataka YamashitaNao HiedaPascal RuffieuxHiroko YamadaRoman FaselNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q José I. Urgel Shantanu Mishra Hironobu Hayashi Jan Wilhelm Carlo A. Pignedoli Marco Di Giovannantonio Roland Widmer Masataka Yamashita Nao Hieda Pascal Ruffieux Hiroko Yamada Roman Fasel On-surface light-induced generation of higher acenes and elucidation of their open-shell character
description	The synthesis of large acenes via traditional solution-chemistry routes is hindered by their poor solubility and high reactivity under ambient conditions. Here, the authors demonstrate the on-surface formation of large acenes, via visible-light-induced photo-dissociation of α-bisdiketone molecular precursors on an Au(111) substrate.
format	article
author	José I. Urgel Shantanu Mishra Hironobu Hayashi Jan Wilhelm Carlo A. Pignedoli Marco Di Giovannantonio Roland Widmer Masataka Yamashita Nao Hieda Pascal Ruffieux Hiroko Yamada Roman Fasel
author_facet	José I. Urgel Shantanu Mishra Hironobu Hayashi Jan Wilhelm Carlo A. Pignedoli Marco Di Giovannantonio Roland Widmer Masataka Yamashita Nao Hieda Pascal Ruffieux Hiroko Yamada Roman Fasel
author_sort	José I. Urgel
title	On-surface light-induced generation of higher acenes and elucidation of their open-shell character
title_short	On-surface light-induced generation of higher acenes and elucidation of their open-shell character
title_full	On-surface light-induced generation of higher acenes and elucidation of their open-shell character
title_fullStr	On-surface light-induced generation of higher acenes and elucidation of their open-shell character
title_full_unstemmed	On-surface light-induced generation of higher acenes and elucidation of their open-shell character
title_sort	on-surface light-induced generation of higher acenes and elucidation of their open-shell character
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/ce348f8f37504e2e98e3aa6b2c2e0184
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On-surface light-induced generation of higher acenes and elucidation of their open-shell character

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