Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing

A simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an incre...

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Autores principales: Han-Wei Chang, Chung-Li Dong, Yan-Hua Chen, Yuan-Zhang Xu, Tzu-Chi Huang, Song-Chi Chen, Feng-Jiin Liu, Yin-Hung Lai, Yu-Chen Tsai
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:ce7b79f159ba41fb868eacbc1a7347ff2021-11-25T18:30:34ZExtended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing10.3390/nano111128812079-4991https://doaj.org/article/ce7b79f159ba41fb868eacbc1a7347ff2021-10-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/2881https://doaj.org/toc/2079-4991A simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an increase in sp<sup>2</sup> carbon bonds in comparison with that of extended graphite. It can be expected to display better electrical conductivity and further promote electron/ion transport kinetics for boosting the electrochemical performance in supercapacitors and glucose sensing. In supercapacitors, MnO<sub>2</sub>/extended graphite delivered an areal capacitance value of 20.4 mF cm<sup>−2</sup> at 0.25 mA cm<sup>−2</sup> current densities and great cycling stability (capacitance retention of 83% after 1000 cycles). In glucose sensing, MnO<sub>2</sub>/extended graphite exhibited a good linear relationship in glucose concentration up to about 5 mM, sensitivity of 43 μA mM<sup>−1</sup>cm<sup>−2</sup>, and the limit of detection of 0.081 mM. It is further concluded that MnO<sub>2</sub>/extended graphite could be a good candidate for the future design of synergistic multifunctional materials in electrochemical techniques.Han-Wei ChangChung-Li DongYan-Hua ChenYuan-Zhang XuTzu-Chi HuangSong-Chi ChenFeng-Jiin LiuYin-Hung LaiYu-Chen TsaiMDPI AGarticleMnO<sub>2</sub>/extended graphitesupercapacitorsglucose sensingChemistryQD1-999ENNanomaterials, Vol 11, Iss 2881, p 2881 (2021)
institution DOAJ
collection DOAJ
language EN
topic MnO<sub>2</sub>/extended graphite
supercapacitors
glucose sensing
Chemistry
QD1-999
spellingShingle MnO<sub>2</sub>/extended graphite
supercapacitors
glucose sensing
Chemistry
QD1-999
Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
description A simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an increase in sp<sup>2</sup> carbon bonds in comparison with that of extended graphite. It can be expected to display better electrical conductivity and further promote electron/ion transport kinetics for boosting the electrochemical performance in supercapacitors and glucose sensing. In supercapacitors, MnO<sub>2</sub>/extended graphite delivered an areal capacitance value of 20.4 mF cm<sup>−2</sup> at 0.25 mA cm<sup>−2</sup> current densities and great cycling stability (capacitance retention of 83% after 1000 cycles). In glucose sensing, MnO<sub>2</sub>/extended graphite exhibited a good linear relationship in glucose concentration up to about 5 mM, sensitivity of 43 μA mM<sup>−1</sup>cm<sup>−2</sup>, and the limit of detection of 0.081 mM. It is further concluded that MnO<sub>2</sub>/extended graphite could be a good candidate for the future design of synergistic multifunctional materials in electrochemical techniques.
format article
author Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
author_facet Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
author_sort Han-Wei Chang
title Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_short Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_full Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_fullStr Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_full_unstemmed Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_sort extended graphite supported flower-like mno<sub>2</sub> as bifunctional materials for supercapacitors and glucose sensing
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/ce7b79f159ba41fb868eacbc1a7347ff
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