Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting
Melting is considered a strictly first-order transition and therefore cannot proceed continuously. Here the authors challenge this concept for long-chain compounds by demonstrating continuous melting of thin layers on graphite where the barrier for such melting, the interface crowding, is removed.
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Nature Portfolio
2021
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oai:doaj.org-article:ce7c540607ec4ad19484511f9ef648f32021-12-02T17:03:35ZQuasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting10.1038/s41467-021-21799-92041-1723https://doaj.org/article/ce7c540607ec4ad19484511f9ef648f32021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21799-9https://doaj.org/toc/2041-1723Melting is considered a strictly first-order transition and therefore cannot proceed continuously. Here the authors challenge this concept for long-chain compounds by demonstrating continuous melting of thin layers on graphite where the barrier for such melting, the interface crowding, is removed.Ruibin ZhangWilliam S. FallKyle Wm. HallGillian A. GehringXiangbing ZengGoran UngarNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021) |
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Science Q Ruibin Zhang William S. Fall Kyle Wm. Hall Gillian A. Gehring Xiangbing Zeng Goran Ungar Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
description |
Melting is considered a strictly first-order transition and therefore cannot proceed continuously. Here the authors challenge this concept for long-chain compounds by demonstrating continuous melting of thin layers on graphite where the barrier for such melting, the interface crowding, is removed. |
format |
article |
author |
Ruibin Zhang William S. Fall Kyle Wm. Hall Gillian A. Gehring Xiangbing Zeng Goran Ungar |
author_facet |
Ruibin Zhang William S. Fall Kyle Wm. Hall Gillian A. Gehring Xiangbing Zeng Goran Ungar |
author_sort |
Ruibin Zhang |
title |
Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
title_short |
Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
title_full |
Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
title_fullStr |
Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
title_full_unstemmed |
Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
title_sort |
quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/ce7c540607ec4ad19484511f9ef648f3 |
work_keys_str_mv |
AT ruibinzhang quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting AT williamsfall quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting AT kylewmhall quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting AT gillianagehring quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting AT xiangbingzeng quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting AT goranungar quasicontinuousmeltingofmodelpolymermonolayerspromptsreinterpretationofpolymermelting |
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1718381934074134528 |