Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology

In the current study, an acrylic polymer binder applicable to road signs was successfully developed by mixing various acrylic, acrylate-type, and photoinitiator-based monomer species at different acrylate series/silicone acrylate ratios. An amorphous acrylic monomer was used, and the distance betwee...

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Autores principales:	Won-Bin Lim, Ji-Hong Bae, Gyu-Hyeok Lee, Ju-Hong Lee, Jin-Gyu Min, PilHo Huh
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	acrylic polymer stimuli responsive polymer external stimuli-responsive material photostimulation binder Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/cf901fe65e854bf0839282718b0ea615
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spelling	oai:doaj.org-article:cf901fe65e854bf0839282718b0ea6152021-11-25T18:13:56ZTransparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology10.3390/ma142268291996-1944https://doaj.org/article/cf901fe65e854bf0839282718b0ea6152021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6829https://doaj.org/toc/1996-1944In the current study, an acrylic polymer binder applicable to road signs was successfully developed by mixing various acrylic, acrylate-type, and photoinitiator-based monomer species at different acrylate series/silicone acrylate ratios. An amorphous acrylic monomer was used, and the distance between the polymers was increased to improve transparency. The binder was designed with the purpose of reducing the yellowing phenomenon due to resonance by excluding the aromatic ring structure, which is the main cause of yellowing. The optical properties of the binder were determined according to the content of n-butyl methacrylate/methyl methacrylate and the composition of the crosslinking agent in the formulation. Allyl glycidyl ether and dilauroyl peroxide were used to improve the yellowing problem of benzoyl peroxide, an aromatic photoinitiator. Adding a silicone-based trivalent acrylic monomer, 3-(trimethoxysilyl)propyl methacrylate (TMSPMA), was also found to have a significant effect on the transparency, shear properties, and water resistance of the binder. When 15 wt% TMSPMA was added, the best water repellency and mechanical properties were exhibited. The surface morphology of the improved binder and the peeling part were confirmed using field emission scanning electron microscopy. The acrylic polymer developed in this study can be applied in the coating and adhesive industries.Won-Bin LimJi-Hong BaeGyu-Hyeok LeeJu-Hong LeeJin-Gyu MinPilHo HuhMDPI AGarticleacrylic polymerstimuli responsive polymerexternal stimuli-responsive materialphotostimulationbinderTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6829, p 6829 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	acrylic polymer stimuli responsive polymer external stimuli-responsive material photostimulation binder Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	acrylic polymer stimuli responsive polymer external stimuli-responsive material photostimulation binder Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Won-Bin Lim Ji-Hong Bae Gyu-Hyeok Lee Ju-Hong Lee Jin-Gyu Min PilHo Huh Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
description	In the current study, an acrylic polymer binder applicable to road signs was successfully developed by mixing various acrylic, acrylate-type, and photoinitiator-based monomer species at different acrylate series/silicone acrylate ratios. An amorphous acrylic monomer was used, and the distance between the polymers was increased to improve transparency. The binder was designed with the purpose of reducing the yellowing phenomenon due to resonance by excluding the aromatic ring structure, which is the main cause of yellowing. The optical properties of the binder were determined according to the content of n-butyl methacrylate/methyl methacrylate and the composition of the crosslinking agent in the formulation. Allyl glycidyl ether and dilauroyl peroxide were used to improve the yellowing problem of benzoyl peroxide, an aromatic photoinitiator. Adding a silicone-based trivalent acrylic monomer, 3-(trimethoxysilyl)propyl methacrylate (TMSPMA), was also found to have a significant effect on the transparency, shear properties, and water resistance of the binder. When 15 wt% TMSPMA was added, the best water repellency and mechanical properties were exhibited. The surface morphology of the improved binder and the peeling part were confirmed using field emission scanning electron microscopy. The acrylic polymer developed in this study can be applied in the coating and adhesive industries.
format	article
author	Won-Bin Lim Ji-Hong Bae Gyu-Hyeok Lee Ju-Hong Lee Jin-Gyu Min PilHo Huh
author_facet	Won-Bin Lim Ji-Hong Bae Gyu-Hyeok Lee Ju-Hong Lee Jin-Gyu Min PilHo Huh
author_sort	Won-Bin Lim
title	Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
title_short	Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
title_full	Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
title_fullStr	Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
title_full_unstemmed	Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology
title_sort	transparency- and repellency-enhanced acrylic-based binder for stimuli-responsive road paint safety improvement technology
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/cf901fe65e854bf0839282718b0ea615
work_keys_str_mv	AT wonbinlim transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology AT jihongbae transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology AT gyuhyeoklee transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology AT juhonglee transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology AT jingyumin transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology AT pilhohuh transparencyandrepellencyenhancedacrylicbasedbinderforstimuliresponsiveroadpaintsafetyimprovementtechnology
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Transparency- and Repellency-Enhanced Acrylic-Based Binder for Stimuli-Responsive Road Paint Safety Improvement Technology

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