Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins

Single-atom Rh catalysts present superior activity in olefins hydroformylation, yet with limited success in regioselectivity control. Here the authors develop a Rh1 single-atom catalyst with nanodiamond as support, with which good to excellent regioselectivities to branched aldehydes in hydroformyla...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Peng Gao, Guanfeng Liang, Tong Ru, Xiaoyan Liu, Haifeng Qi, Aiqin Wang, Fen-Er Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d02d2974b79048ec9dbcd1ea9ffaadc3
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:d02d2974b79048ec9dbcd1ea9ffaadc3
record_format	dspace
spelling	oai:doaj.org-article:d02d2974b79048ec9dbcd1ea9ffaadc32021-12-02T18:49:17ZPhosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins10.1038/s41467-021-25061-02041-1723https://doaj.org/article/d02d2974b79048ec9dbcd1ea9ffaadc32021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25061-0https://doaj.org/toc/2041-1723Single-atom Rh catalysts present superior activity in olefins hydroformylation, yet with limited success in regioselectivity control. Here the authors develop a Rh1 single-atom catalyst with nanodiamond as support, with which good to excellent regioselectivities to branched aldehydes in hydroformylation of terminal olefins are achieved.Peng GaoGuanfeng LiangTong RuXiaoyan LiuHaifeng QiAiqin WangFen-Er ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Peng Gao Guanfeng Liang Tong Ru Xiaoyan Liu Haifeng Qi Aiqin Wang Fen-Er Chen Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
description	Single-atom Rh catalysts present superior activity in olefins hydroformylation, yet with limited success in regioselectivity control. Here the authors develop a Rh1 single-atom catalyst with nanodiamond as support, with which good to excellent regioselectivities to branched aldehydes in hydroformylation of terminal olefins are achieved.
format	article
author	Peng Gao Guanfeng Liang Tong Ru Xiaoyan Liu Haifeng Qi Aiqin Wang Fen-Er Chen
author_facet	Peng Gao Guanfeng Liang Tong Ru Xiaoyan Liu Haifeng Qi Aiqin Wang Fen-Er Chen
author_sort	Peng Gao
title	Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
title_short	Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
title_full	Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
title_fullStr	Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
title_full_unstemmed	Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
title_sort	phosphorus coordinated rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d02d2974b79048ec9dbcd1ea9ffaadc3
work_keys_str_mv	AT penggao phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT guanfengliang phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT tongru phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT xiaoyanliu phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT haifengqi phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT aiqinwang phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins AT fenerchen phosphoruscoordinatedrhsingleatomsitesonnanodiamondashighlyregioselectivecatalystforhydroformylationofolefins
_version_	1718377591348396032

Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins

Ejemplares similares