Depleted depletion drives polymer swelling in poor solvent mixtures

Whilst polymer collapse in a single poor solvent is well understood, polymer swelling in mixtures of two repulsive solvents is surprising. Here, the authors unveil the microscopic origin of collapse-swelling-collapse behaviour, showing how it emerges at constant pressure when a balance of depletion...

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Autores principales:	Debashish Mukherji, Carlos M. Marques, Torsten Stuehn, Kurt Kremer
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d05d6e73d87446ffa9354d91690e206f
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spelling	oai:doaj.org-article:d05d6e73d87446ffa9354d91690e206f2021-12-02T14:40:26ZDepleted depletion drives polymer swelling in poor solvent mixtures10.1038/s41467-017-01520-52041-1723https://doaj.org/article/d05d6e73d87446ffa9354d91690e206f2017-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01520-5https://doaj.org/toc/2041-1723Whilst polymer collapse in a single poor solvent is well understood, polymer swelling in mixtures of two repulsive solvents is surprising. Here, the authors unveil the microscopic origin of collapse-swelling-collapse behaviour, showing how it emerges at constant pressure when a balance of depletion interactions is achieved.Debashish MukherjiCarlos M. MarquesTorsten StuehnKurt KremerNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Debashish Mukherji Carlos M. Marques Torsten Stuehn Kurt Kremer Depleted depletion drives polymer swelling in poor solvent mixtures
description	Whilst polymer collapse in a single poor solvent is well understood, polymer swelling in mixtures of two repulsive solvents is surprising. Here, the authors unveil the microscopic origin of collapse-swelling-collapse behaviour, showing how it emerges at constant pressure when a balance of depletion interactions is achieved.
format	article
author	Debashish Mukherji Carlos M. Marques Torsten Stuehn Kurt Kremer
author_facet	Debashish Mukherji Carlos M. Marques Torsten Stuehn Kurt Kremer
author_sort	Debashish Mukherji
title	Depleted depletion drives polymer swelling in poor solvent mixtures
title_short	Depleted depletion drives polymer swelling in poor solvent mixtures
title_full	Depleted depletion drives polymer swelling in poor solvent mixtures
title_fullStr	Depleted depletion drives polymer swelling in poor solvent mixtures
title_full_unstemmed	Depleted depletion drives polymer swelling in poor solvent mixtures
title_sort	depleted depletion drives polymer swelling in poor solvent mixtures
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/d05d6e73d87446ffa9354d91690e206f
work_keys_str_mv	AT debashishmukherji depleteddepletiondrivespolymerswellinginpoorsolventmixtures AT carlosmmarques depleteddepletiondrivespolymerswellinginpoorsolventmixtures AT torstenstuehn depleteddepletiondrivespolymerswellinginpoorsolventmixtures AT kurtkremer depleteddepletiondrivespolymerswellinginpoorsolventmixtures
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Depleted depletion drives polymer swelling in poor solvent mixtures

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