Depleted depletion drives polymer swelling in poor solvent mixtures
Whilst polymer collapse in a single poor solvent is well understood, polymer swelling in mixtures of two repulsive solvents is surprising. Here, the authors unveil the microscopic origin of collapse-swelling-collapse behaviour, showing how it emerges at constant pressure when a balance of depletion...
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| Main Authors: | , , , |
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| Format: | article |
| Language: | EN |
| Published: |
Nature Portfolio
2017
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| Subjects: | |
| Online Access: | https://doaj.org/article/d05d6e73d87446ffa9354d91690e206f |
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