Depleted depletion drives polymer swelling in poor solvent mixtures
Whilst polymer collapse in a single poor solvent is well understood, polymer swelling in mixtures of two repulsive solvents is surprising. Here, the authors unveil the microscopic origin of collapse-swelling-collapse behaviour, showing how it emerges at constant pressure when a balance of depletion...
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Autores principales: | Debashish Mukherji, Carlos M. Marques, Torsten Stuehn, Kurt Kremer |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2017
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Materias: | |
Acceso en línea: | https://doaj.org/article/d05d6e73d87446ffa9354d91690e206f |
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