From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts

From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts

The design, synthesis, commercialization and application of air-stable Ni(II)/Josiphos complexes has been realized in a collaboration between Solvias and ICBMS (University Lyon 1). The Ni-complexes are utilized as versatile precatalysts for diverse cross-coupling reactions. Apart from being active i...

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Autores principales: Florian Bächle, Achim Link, Abderrahmane Amgoune, Anis Tlili
Formato: article
Lenguaje:DE
EN
FR
Publicado: Swiss Chemical Society 2021
Materias:
acetone
ammonia
catalysis
josiphos
nickel
Chemistry
QD1-999
Acceso en línea:https://doaj.org/article/d082c265a9ac46e7948ebc179da9eca9
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spelling oai:doaj.org-article:d082c265a9ac46e7948ebc179da9eca92021-11-26T10:05:23ZFrom Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts10.2533/chimia.2021.9430009-42932673-2424https://doaj.org/article/d082c265a9ac46e7948ebc179da9eca92021-11-01T00:00:00Zhttps://doaj.org/toc/0009-4293https://doaj.org/toc/2673-2424The design, synthesis, commercialization and application of air-stable Ni(II)/Josiphos complexes has been realized in a collaboration between Solvias and ICBMS (University Lyon 1). The Ni-complexes are utilized as versatile precatalysts for diverse cross-coupling reactions. Apart from being active in established C–C and C–N couplings at low catalyst loadings, the novel Ni-precatalysts enabled the development of the challenging monoarylation of ammonia, ammonia surrogates and even alkylammonium chlorides with aryl carbamates. Finally, the α-arylation of acetone with aryl chlorides, carbamates and pivalates was demonstrated using the Ni(II)/Josiphos precatalysts.Florian BächleAchim LinkAbderrahmane AmgouneAnis TliliSwiss Chemical SocietyarticleacetoneammoniacatalysisjosiphosnickelChemistryQD1-999DEENFRCHIMIA, Vol 75, Iss 11, Pp 943-947 (2021)
institution DOAJ
collection DOAJ
language DE
EN
FR
topic acetone
ammonia
catalysis
josiphos
nickel
Chemistry
QD1-999
spellingShingle acetone
ammonia
catalysis
josiphos
nickel
Chemistry
QD1-999
Florian Bächle
Achim Link
Abderrahmane Amgoune
Anis Tlili
From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
description The design, synthesis, commercialization and application of air-stable Ni(II)/Josiphos complexes has been realized in a collaboration between Solvias and ICBMS (University Lyon 1). The Ni-complexes are utilized as versatile precatalysts for diverse cross-coupling reactions. Apart from being active in established C–C and C–N couplings at low catalyst loadings, the novel Ni-precatalysts enabled the development of the challenging monoarylation of ammonia, ammonia surrogates and even alkylammonium chlorides with aryl carbamates. Finally, the α-arylation of acetone with aryl chlorides, carbamates and pivalates was demonstrated using the Ni(II)/Josiphos precatalysts.
format article
author Florian Bächle
Achim Link
Abderrahmane Amgoune
Anis Tlili
author_facet Florian Bächle
Achim Link
Abderrahmane Amgoune
Anis Tlili
author_sort Florian Bächle
title From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
title_short From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
title_full From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
title_fullStr From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
title_full_unstemmed From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
title_sort from academia to the market – air-stable ni(ii)/josiphos catalysts
publisher Swiss Chemical Society
publishDate 2021
url https://doaj.org/article/d082c265a9ac46e7948ebc179da9eca9
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AT abderrahmaneamgoune fromacademiatothemarketairstableniiijosiphoscatalysts
AT anistlili fromacademiatothemarketairstableniiijosiphoscatalysts
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