Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment

This study demonstrated the synthesis of o-carboxymethyl chitosan (CMC)-stabilized zinc oxide nanocomposites (ZnO NCs) combined with aqueous leaves extracts of hydroponically cultured ginseng and used as a photocatalyst for the degradation of hazardous dyes, including malachite green (MG), rhodamine...

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Autores principales: Yinping Jin, Ling Li, Reshmi Akter, Esrat Jahan Rupa, Deok-Chun Yang, Se Chan Kang, Hao Zhang
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:d095b9199275453d8da1e6809c9eddd32021-11-11T18:07:31ZHydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment10.3390/ma142165571996-1944https://doaj.org/article/d095b9199275453d8da1e6809c9eddd32021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6557https://doaj.org/toc/1996-1944This study demonstrated the synthesis of o-carboxymethyl chitosan (CMC)-stabilized zinc oxide nanocomposites (ZnO NCs) combined with aqueous leaves extracts of hydroponically cultured ginseng and used as a photocatalyst for the degradation of hazardous dyes, including malachite green (MG), rhodamine B (RB), and congo red (CR) under ultraviolet illumination. Hydroponic ginseng leaves contain bioactive components, namely ginsenoside and natural polyphenol, which prompt ginseng’s biological effect. Besides, the CMC polymer is naturally biodegradable, stabilizes the nanoformation and enhances the solubility of ginsenoside. The hydroponic ginseng leaves zinc oxide CMC nanocomposites (GL–CMC–ZnO NCs) were synthesized using the co-precipitation method and characterized using different analytical methods. The FTIR analysis identified significant phytochemicals in the leaves extracts and cotton-shape morphology observed using FE-TEM analysis. The XRD analysis also determined that the crystallite size was 28 nm. The photocatalyst degraded CR, RB, and MG dyes by approximately 87%, 94%, and 96% within contact times of 10, 20, 25, and 30 min, respectively, when the dye concentration was 15 mg/L. As far as our knowledge, this is the first report on hydroponic ginseng NCs incorporated with the CMC polymer for the degradation of hazardous dyes on wastewater treatment. This study can add significant value to large-scale wastewater treatment.Yinping JinLing LiReshmi AkterEsrat Jahan RupaDeok-Chun YangSe Chan KangHao ZhangMDPI AGarticlehydroponic ginsengo-carboxymethyl chitosan (CMC)ZnOdye degradationwater treatmentTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6557, p 6557 (2021)
institution DOAJ
collection DOAJ
language EN
topic hydroponic ginseng
o-carboxymethyl chitosan (CMC)
ZnO
dye degradation
water treatment
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle hydroponic ginseng
o-carboxymethyl chitosan (CMC)
ZnO
dye degradation
water treatment
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Yinping Jin
Ling Li
Reshmi Akter
Esrat Jahan Rupa
Deok-Chun Yang
Se Chan Kang
Hao Zhang
Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
description This study demonstrated the synthesis of o-carboxymethyl chitosan (CMC)-stabilized zinc oxide nanocomposites (ZnO NCs) combined with aqueous leaves extracts of hydroponically cultured ginseng and used as a photocatalyst for the degradation of hazardous dyes, including malachite green (MG), rhodamine B (RB), and congo red (CR) under ultraviolet illumination. Hydroponic ginseng leaves contain bioactive components, namely ginsenoside and natural polyphenol, which prompt ginseng’s biological effect. Besides, the CMC polymer is naturally biodegradable, stabilizes the nanoformation and enhances the solubility of ginsenoside. The hydroponic ginseng leaves zinc oxide CMC nanocomposites (GL–CMC–ZnO NCs) were synthesized using the co-precipitation method and characterized using different analytical methods. The FTIR analysis identified significant phytochemicals in the leaves extracts and cotton-shape morphology observed using FE-TEM analysis. The XRD analysis also determined that the crystallite size was 28 nm. The photocatalyst degraded CR, RB, and MG dyes by approximately 87%, 94%, and 96% within contact times of 10, 20, 25, and 30 min, respectively, when the dye concentration was 15 mg/L. As far as our knowledge, this is the first report on hydroponic ginseng NCs incorporated with the CMC polymer for the degradation of hazardous dyes on wastewater treatment. This study can add significant value to large-scale wastewater treatment.
format article
author Yinping Jin
Ling Li
Reshmi Akter
Esrat Jahan Rupa
Deok-Chun Yang
Se Chan Kang
Hao Zhang
author_facet Yinping Jin
Ling Li
Reshmi Akter
Esrat Jahan Rupa
Deok-Chun Yang
Se Chan Kang
Hao Zhang
author_sort Yinping Jin
title Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
title_short Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
title_full Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
title_fullStr Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
title_full_unstemmed Hydroponic Cultured Ginseng Leaves Zinc Oxides Nanocomposite Stabilized with CMC Polymer for Degradation of Hazardous Dyes in Wastewater Treatment
title_sort hydroponic cultured ginseng leaves zinc oxides nanocomposite stabilized with cmc polymer for degradation of hazardous dyes in wastewater treatment
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/d095b9199275453d8da1e6809c9eddd3
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