Universal kinetics of imperfect reactions in confinement
Chemical reactions often require multiple random encounters between reactants, but a general, analytical treatment such imperfect transport-limited/influenced reactions in confined spaces has not yet been proposed. Here, the authors predict the full kinetics of these reactions for Markovian processe...
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Nature Portfolio
2021
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oai:doaj.org-article:d1f1cb9b027f4cfeae0265c66911a15c2021-11-14T12:07:18ZUniversal kinetics of imperfect reactions in confinement10.1038/s42004-021-00591-22399-3669https://doaj.org/article/d1f1cb9b027f4cfeae0265c66911a15c2021-11-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00591-2https://doaj.org/toc/2399-3669Chemical reactions often require multiple random encounters between reactants, but a general, analytical treatment such imperfect transport-limited/influenced reactions in confined spaces has not yet been proposed. Here, the authors predict the full kinetics of these reactions for Markovian processes in large confining volumes.Thomas GuérinMaxim DolgushevOlivier BénichouRaphaël VoituriezNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021) |
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Chemistry QD1-999 |
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Chemistry QD1-999 Thomas Guérin Maxim Dolgushev Olivier Bénichou Raphaël Voituriez Universal kinetics of imperfect reactions in confinement |
description |
Chemical reactions often require multiple random encounters between reactants, but a general, analytical treatment such imperfect transport-limited/influenced reactions in confined spaces has not yet been proposed. Here, the authors predict the full kinetics of these reactions for Markovian processes in large confining volumes. |
format |
article |
author |
Thomas Guérin Maxim Dolgushev Olivier Bénichou Raphaël Voituriez |
author_facet |
Thomas Guérin Maxim Dolgushev Olivier Bénichou Raphaël Voituriez |
author_sort |
Thomas Guérin |
title |
Universal kinetics of imperfect reactions in confinement |
title_short |
Universal kinetics of imperfect reactions in confinement |
title_full |
Universal kinetics of imperfect reactions in confinement |
title_fullStr |
Universal kinetics of imperfect reactions in confinement |
title_full_unstemmed |
Universal kinetics of imperfect reactions in confinement |
title_sort |
universal kinetics of imperfect reactions in confinement |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/d1f1cb9b027f4cfeae0265c66911a15c |
work_keys_str_mv |
AT thomasguerin universalkineticsofimperfectreactionsinconfinement AT maximdolgushev universalkineticsofimperfectreactionsinconfinement AT olivierbenichou universalkineticsofimperfectreactionsinconfinement AT raphaelvoituriez universalkineticsofimperfectreactionsinconfinement |
_version_ |
1718429433409306624 |