Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids

Lubricant additive technology to improve lubricant performances is an important issue for ionic liquids to be applied practically. Effects of carboxylic acids with different carbon chain length in ionic liquid on tribological properties were examined. Solubility of carboxylic acids was dependent on...

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Autores principales: Hideto Kamimura, Takeru Chiba, Naoko Watanabe, Tomoo Kubo, Hidetaka Nanao, Ichiro Minami, Shigeyuki Mori
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Publicado: Japanese Society of Tribologists 2006
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Acceso en línea:https://doaj.org/article/d1faefe4df5d4abbbb12ccbde6c28169
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spelling oai:doaj.org-article:d1faefe4df5d4abbbb12ccbde6c281692021-11-05T09:30:22ZEffects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids1881-219810.2474/trol.1.40https://doaj.org/article/d1faefe4df5d4abbbb12ccbde6c281692006-11-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/1/2/1_2_40/_pdf/-char/enhttps://doaj.org/toc/1881-2198Lubricant additive technology to improve lubricant performances is an important issue for ionic liquids to be applied practically. Effects of carboxylic acids with different carbon chain length in ionic liquid on tribological properties were examined. Solubility of carboxylic acids was dependent on the chain length of carboxylic acids and imidazolium cations. The carboxylic acids reduced friction and wear in comparison with additive free one. It was found that friction reducing properties of carboxylic acid depended on their chain length. Interestingly, additive response of ionic liquids was found to be superior to those for conventional ester oil as base oil. Surface images obtained by an optical microscope clearly show that the additive depressed chemical wear by ionic liquids especially at low load. Surface analysis with EPMA supported films of carboxylic acids as a cause of improvement of friction property. Therefore, the mechanism of carboxylic acids was considered to provide adsorbed film which accompanied with low friction and anti-wear properties.Hideto KamimuraTakeru ChibaNaoko WatanabeTomoo KuboHidetaka NanaoIchiro MinamiShigeyuki MoriJapanese Society of Tribologistsarticleionic liquidadditivefatty acidoilinessweartribochemical reactionboundary lubricationPhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 1, Iss 2, Pp 40-43 (2006)
institution DOAJ
collection DOAJ
language EN
topic ionic liquid
additive
fatty acid
oiliness
wear
tribochemical reaction
boundary lubrication
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
spellingShingle ionic liquid
additive
fatty acid
oiliness
wear
tribochemical reaction
boundary lubrication
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
Hideto Kamimura
Takeru Chiba
Naoko Watanabe
Tomoo Kubo
Hidetaka Nanao
Ichiro Minami
Shigeyuki Mori
Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
description Lubricant additive technology to improve lubricant performances is an important issue for ionic liquids to be applied practically. Effects of carboxylic acids with different carbon chain length in ionic liquid on tribological properties were examined. Solubility of carboxylic acids was dependent on the chain length of carboxylic acids and imidazolium cations. The carboxylic acids reduced friction and wear in comparison with additive free one. It was found that friction reducing properties of carboxylic acid depended on their chain length. Interestingly, additive response of ionic liquids was found to be superior to those for conventional ester oil as base oil. Surface images obtained by an optical microscope clearly show that the additive depressed chemical wear by ionic liquids especially at low load. Surface analysis with EPMA supported films of carboxylic acids as a cause of improvement of friction property. Therefore, the mechanism of carboxylic acids was considered to provide adsorbed film which accompanied with low friction and anti-wear properties.
format article
author Hideto Kamimura
Takeru Chiba
Naoko Watanabe
Tomoo Kubo
Hidetaka Nanao
Ichiro Minami
Shigeyuki Mori
author_facet Hideto Kamimura
Takeru Chiba
Naoko Watanabe
Tomoo Kubo
Hidetaka Nanao
Ichiro Minami
Shigeyuki Mori
author_sort Hideto Kamimura
title Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
title_short Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
title_full Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
title_fullStr Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
title_full_unstemmed Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids
title_sort effects of carboxylic acids on friction and wear reducing properties for alkylmethylimidazolium derived ionic liquids
publisher Japanese Society of Tribologists
publishDate 2006
url https://doaj.org/article/d1faefe4df5d4abbbb12ccbde6c28169
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AT takeruchiba effectsofcarboxylicacidsonfrictionandwearreducingpropertiesforalkylmethylimidazoliumderivedionicliquids
AT naokowatanabe effectsofcarboxylicacidsonfrictionandwearreducingpropertiesforalkylmethylimidazoliumderivedionicliquids
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