Eu3+ photoluminescence in mononuclear coordination compounds with different ligands

Novel Eu3+-based photoluminescent (PL) organic coordination compounds have been synthesized; their optical properties in the UV–Vis spectrum have been characterized. The paper presents results of studying mononuclear coordination compounds (MCCs) with the Eu3+ ion, namely, Eu(o-MBA)3Phen, Eu(TTA)3(P...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autor principal:	Bordian, Olga
Formato:	article
Lenguaje:	EN
Publicado:	D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2018
Materias:	Physics QC1-999 Electronics TK7800-8360
Acceso en línea:	https://doaj.org/article/d212e2e274a0400c95045f9d0db4d951
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:d212e2e274a0400c95045f9d0db4d951
record_format	dspace
spelling	oai:doaj.org-article:d212e2e274a0400c95045f9d0db4d9512021-11-21T11:56:11Z Eu3+ photoluminescence in mononuclear coordination compounds with different ligands535.37+539.192537-63651810-648Xhttps://doaj.org/article/d212e2e274a0400c95045f9d0db4d9512018-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2018/article/71376https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Novel Eu3+-based photoluminescent (PL) organic coordination compounds have been synthesized; their optical properties in the UV–Vis spectrum have been characterized. The paper presents results of studying mononuclear coordination compounds (MCCs) with the Eu3+ ion, namely, Eu(o-MBA)3Phen, Eu(TTA)3(Ph3PO)2, Eu(DBM)3Phen, and Eu(DBM)3(Ph3PO)1H2O. The energy of the absorption threshold (Eg) for all the studied ligands has been found to be greater than the energy required for excitation of the 7F0→5D0 transitions within the transitions 4f orbital of the Eu3+ ion. The PL emission spectra of the studied coordination compounds are associated with the internal transitions of the Eu3+: 5D0→7Fi (i = 0, 1, 2, 3, 4). Emission peak positions in the PL spectra are registered around 537, 580, 612, 650, and 702 nm. The FWHM of the dominant PL band at 612 nm is less than 10 nm; this finding indicates that MCCs exhibit atomic-like fluorescence emission and color purity.Bordian, OlgaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 17, Iss 3-4, Pp 167-176 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physics QC1-999 Electronics TK7800-8360
spellingShingle	Physics QC1-999 Electronics TK7800-8360 Bordian, Olga Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
description	Novel Eu3+-based photoluminescent (PL) organic coordination compounds have been synthesized; their optical properties in the UV–Vis spectrum have been characterized. The paper presents results of studying mononuclear coordination compounds (MCCs) with the Eu3+ ion, namely, Eu(o-MBA)3Phen, Eu(TTA)3(Ph3PO)2, Eu(DBM)3Phen, and Eu(DBM)3(Ph3PO)1H2O. The energy of the absorption threshold (Eg) for all the studied ligands has been found to be greater than the energy required for excitation of the 7F0→5D0 transitions within the transitions 4f orbital of the Eu3+ ion. The PL emission spectra of the studied coordination compounds are associated with the internal transitions of the Eu3+: 5D0→7Fi (i = 0, 1, 2, 3, 4). Emission peak positions in the PL spectra are registered around 537, 580, 612, 650, and 702 nm. The FWHM of the dominant PL band at 612 nm is less than 10 nm; this finding indicates that MCCs exhibit atomic-like fluorescence emission and color purity.
format	article
author	Bordian, Olga
author_facet	Bordian, Olga
author_sort	Bordian, Olga
title	Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
title_short	Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
title_full	Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
title_fullStr	Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
title_full_unstemmed	Eu3+ photoluminescence in mononuclear coordination compounds with different ligands
title_sort	eu3+ photoluminescence in mononuclear coordination compounds with different ligands
publisher	D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate	2018
url	https://doaj.org/article/d212e2e274a0400c95045f9d0db4d951
work_keys_str_mv	AT bordianolga eu3photoluminescenceinmononuclearcoordinationcompoundswithdifferentligands
_version_	1718419391157108736

Eu3+ photoluminescence in mononuclear coordination compounds with different ligands

Ejemplares similares