Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage

While metal–organic frameworks exhibit record-breaking gas storage capacities, their typically powdered form hinders their industrial applicability. Here, the authors engineer UiO-66 into centimetre-sized monoliths with optimal pore-size distributions, achieving benchmark volumetric working capaciti...

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Autores principales: B. M. Connolly, M. Aragones-Anglada, J. Gandara-Loe, N. A. Danaf, D. C. Lamb, J. P. Mehta, D. Vulpe, S. Wuttke, J. Silvestre-Albero, P. Z. Moghadam, A. E. H. Wheatley, D. Fairen-Jimenez
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/d26126a6d258435eaf2f8eb5d1c5f7e8
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Sumario:While metal–organic frameworks exhibit record-breaking gas storage capacities, their typically powdered form hinders their industrial applicability. Here, the authors engineer UiO-66 into centimetre-sized monoliths with optimal pore-size distributions, achieving benchmark volumetric working capacities for both CH4 and CO2.