Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain

The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.

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Autores principales: Chirranjeevi Balaji Gopal, Max García-Melchor, Sang Chul Lee, Yezhou Shi, Andrey Shavorskiy, Matteo Monti, Zixuan Guan, Robert Sinclair, Hendrik Bluhm, Aleksandra Vojvodic, William C. Chueh
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Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb9
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spelling oai:doaj.org-article:d263b7387b6149c1a05806e5b6313eb92021-12-02T14:40:56ZEquilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain10.1038/ncomms153602041-1723https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb92017-05-01T00:00:00Zhttps://doi.org/10.1038/ncomms15360https://doaj.org/toc/2041-1723The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.Chirranjeevi Balaji GopalMax García-MelchorSang Chul LeeYezhou ShiAndrey ShavorskiyMatteo MontiZixuan GuanRobert SinclairHendrik BluhmAleksandra VojvodicWilliam C. ChuehNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Chirranjeevi Balaji Gopal
Max García-Melchor
Sang Chul Lee
Yezhou Shi
Andrey Shavorskiy
Matteo Monti
Zixuan Guan
Robert Sinclair
Hendrik Bluhm
Aleksandra Vojvodic
William C. Chueh
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
description The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.
format article
author Chirranjeevi Balaji Gopal
Max García-Melchor
Sang Chul Lee
Yezhou Shi
Andrey Shavorskiy
Matteo Monti
Zixuan Guan
Robert Sinclair
Hendrik Bluhm
Aleksandra Vojvodic
William C. Chueh
author_facet Chirranjeevi Balaji Gopal
Max García-Melchor
Sang Chul Lee
Yezhou Shi
Andrey Shavorskiy
Matteo Monti
Zixuan Guan
Robert Sinclair
Hendrik Bluhm
Aleksandra Vojvodic
William C. Chueh
author_sort Chirranjeevi Balaji Gopal
title Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
title_short Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
title_full Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
title_fullStr Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
title_full_unstemmed Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
title_sort equilibrium oxygen storage capacity of ultrathin ceo2-δ depends non-monotonically on large biaxial strain
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb9
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