Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides

Important applications of transition metal carbides (TMCs) are as wear resistant composite layers deposited by plasma transferred arc welding (PTAW) and laser methods. Growing interest in them has also been observed in additive manufacturing and in HEA technology (bulk composite materials and layers...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Mariusz Bober, Jacek Senkara, Hong Li
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	transition metal carbides NiBSi alloy phase interaction PTAW composite layers Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/d26e5697d30344f782e718face4e3c86
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:d26e5697d30344f782e718face4e3c86
record_format	dspace
spelling	oai:doaj.org-article:d26e5697d30344f782e718face4e3c862021-11-11T18:09:03ZComparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides10.3390/ma142166171996-1944https://doaj.org/article/d26e5697d30344f782e718face4e3c862021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6617https://doaj.org/toc/1996-1944Important applications of transition metal carbides (TMCs) are as wear resistant composite layers deposited by plasma transferred arc welding (PTAW) and laser methods. Growing interest in them has also been observed in additive manufacturing and in HEA technology (bulk composite materials and layers), and in the area of energy conversion and storage. This paper presents the results of comparative studies on interfacial interactions in the NiBSi−TMCs system for two border IVB and VIB TM groups of the periodic table. Model (wettability and spreadability) and application experiments (testing of the PTAW-obtained carbide particle−matrix boundaries) were performed. Fe from partially melted steel substrates is active in the liquid NiBSi−TMCs system. It was revealed that the interaction of TMCs with the liquid NiBSi matrix tends to increase with the group number, and from the top to bottom inside individual groups. Particles of IVB TMCs are decomposed by penetration of the liquid along the grain boundaries, whereas those of VIB are decomposed by solubility in the matrix and secondary crystallization. No transition zones formed at the interfacial boundaries of the matrix−IVB group TMCs, unlike in the case of the VIB group. The experimental results are discussed using the data on the TMC electronic structure and the physicochemical properties.Mariusz BoberJacek SenkaraHong LiMDPI AGarticletransition metal carbidesNiBSi alloyphase interactionPTAWcomposite layersTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6617, p 6617 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	transition metal carbides NiBSi alloy phase interaction PTAW composite layers Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	transition metal carbides NiBSi alloy phase interaction PTAW composite layers Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Mariusz Bober Jacek Senkara Hong Li Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
description	Important applications of transition metal carbides (TMCs) are as wear resistant composite layers deposited by plasma transferred arc welding (PTAW) and laser methods. Growing interest in them has also been observed in additive manufacturing and in HEA technology (bulk composite materials and layers), and in the area of energy conversion and storage. This paper presents the results of comparative studies on interfacial interactions in the NiBSi−TMCs system for two border IVB and VIB TM groups of the periodic table. Model (wettability and spreadability) and application experiments (testing of the PTAW-obtained carbide particle−matrix boundaries) were performed. Fe from partially melted steel substrates is active in the liquid NiBSi−TMCs system. It was revealed that the interaction of TMCs with the liquid NiBSi matrix tends to increase with the group number, and from the top to bottom inside individual groups. Particles of IVB TMCs are decomposed by penetration of the liquid along the grain boundaries, whereas those of VIB are decomposed by solubility in the matrix and secondary crystallization. No transition zones formed at the interfacial boundaries of the matrix−IVB group TMCs, unlike in the case of the VIB group. The experimental results are discussed using the data on the TMC electronic structure and the physicochemical properties.
format	article
author	Mariusz Bober Jacek Senkara Hong Li
author_facet	Mariusz Bober Jacek Senkara Hong Li
author_sort	Mariusz Bober
title	Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
title_short	Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
title_full	Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
title_fullStr	Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
title_full_unstemmed	Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides
title_sort	comparative analysis of the phase interaction in plasma surfaced nibsi overlays with ivb and vib transition metal carbides
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/d26e5697d30344f782e718face4e3c86
work_keys_str_mv	AT mariuszbober comparativeanalysisofthephaseinteractioninplasmasurfacednibsioverlayswithivbandvibtransitionmetalcarbides AT jaceksenkara comparativeanalysisofthephaseinteractioninplasmasurfacednibsioverlayswithivbandvibtransitionmetalcarbides AT hongli comparativeanalysisofthephaseinteractioninplasmasurfacednibsioverlayswithivbandvibtransitionmetalcarbides
_version_	1718431970626633728

Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides

Ejemplares similares