Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand

The novel nickel(II) complex has been successfully synthesized through the reaction of Ni(NO3)2·6H2O with 4-aminoantipyrine (AAP) ligand in a 1:3 mole ratio of Ni(II) to AAP. The complex was characterized using UV-Vis, Atomic Absorption Spectroscopy (AAS), Infrared spectrophotometry (IR), Thermograv...

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Autores principales:	Yusica Amalia Rasyda, Mudhita Kusuma Widowati, Soerya Dewi Marliyana, Sentot Budi Rahardjo
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2021
Materias:	nickel(ii) 4-aminoantipyrine complex antibacterial activity Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/d276707b7661435e8a4af65b6e93b4bb
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spelling	oai:doaj.org-article:d276707b7661435e8a4af65b6e93b4bb2021-12-02T12:51:19ZSynthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand1411-94202460-157810.22146/ijc.56552https://doaj.org/article/d276707b7661435e8a4af65b6e93b4bb2021-02-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/56552https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The novel nickel(II) complex has been successfully synthesized through the reaction of Ni(NO3)2·6H2O with 4-aminoantipyrine (AAP) ligand in a 1:3 mole ratio of Ni(II) to AAP. The complex was characterized using UV-Vis, Atomic Absorption Spectroscopy (AAS), Infrared spectrophotometry (IR), Thermogravimetry/Differential Scanning Calorimetry (TG/DSC), conductivity, and magnetic susceptibility. The complex formula was [Ni(AAP)3](NO3)2·5H2O. AAP was a bidentate ligand that coordinated through the primary amine nitrogen and the carbonyl oxygen to the nickel ion. The electronic spectra of the complex displayed two peaks at 646 nm and 385 nm in accordance with the 3A2g(F) → 3T1g(F) and 3A2g(F) → 3T1g(P) transitions, respectively. This complex gave a paramagnetic property with the effective magnetic moment (µeff) of 2.96 BM and the shape of an octahedron. The antibacterial test of this complex showed higher activity than the metal and its free ligand.Yusica Amalia RasydaMudhita Kusuma WidowatiSoerya Dewi MarliyanaSentot Budi RahardjoDepartment of Chemistry, Universitas Gadjah Madaarticlenickel(ii)4-aminoantipyrinecomplexantibacterial activityChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 2, Pp 391-399 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	nickel(ii) 4-aminoantipyrine complex antibacterial activity Chemistry QD1-999
spellingShingle	nickel(ii) 4-aminoantipyrine complex antibacterial activity Chemistry QD1-999 Yusica Amalia Rasyda Mudhita Kusuma Widowati Soerya Dewi Marliyana Sentot Budi Rahardjo Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
description	The novel nickel(II) complex has been successfully synthesized through the reaction of Ni(NO3)2·6H2O with 4-aminoantipyrine (AAP) ligand in a 1:3 mole ratio of Ni(II) to AAP. The complex was characterized using UV-Vis, Atomic Absorption Spectroscopy (AAS), Infrared spectrophotometry (IR), Thermogravimetry/Differential Scanning Calorimetry (TG/DSC), conductivity, and magnetic susceptibility. The complex formula was [Ni(AAP)3](NO3)2·5H2O. AAP was a bidentate ligand that coordinated through the primary amine nitrogen and the carbonyl oxygen to the nickel ion. The electronic spectra of the complex displayed two peaks at 646 nm and 385 nm in accordance with the 3A2g(F) → 3T1g(F) and 3A2g(F) → 3T1g(P) transitions, respectively. This complex gave a paramagnetic property with the effective magnetic moment (µeff) of 2.96 BM and the shape of an octahedron. The antibacterial test of this complex showed higher activity than the metal and its free ligand.
format	article
author	Yusica Amalia Rasyda Mudhita Kusuma Widowati Soerya Dewi Marliyana Sentot Budi Rahardjo
author_facet	Yusica Amalia Rasyda Mudhita Kusuma Widowati Soerya Dewi Marliyana Sentot Budi Rahardjo
author_sort	Yusica Amalia Rasyda
title	Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
title_short	Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
title_full	Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
title_fullStr	Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
title_full_unstemmed	Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand
title_sort	synthesis, characterization and antibacterial properties of nickel(ii) complex with 4-aminoantipyrine ligand
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2021
url	https://doaj.org/article/d276707b7661435e8a4af65b6e93b4bb
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Synthesis, Characterization and Antibacterial Properties of Nickel(II) Complex with 4-Aminoantipyrine Ligand

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