Halogen bonding as a supramolecular dynamics catalyst

The halogen bond is well known for its ability to assemble supramolecules. Here, using NMR experiments, the authors reveal the role of these bonds in dynamic processes, finding that the halogen bond directly catalyzes dynamical rotation in solid cocrystals by reducing the associated energy barrier.

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Detalles Bibliográficos
Autores principales:	Patrick M. J. Szell, Scott Zablotny, David L. Bryce
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d30d0d8031994a8a983a53f2264b20ec
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spelling	oai:doaj.org-article:d30d0d8031994a8a983a53f2264b20ec2021-12-02T17:01:51ZHalogen bonding as a supramolecular dynamics catalyst10.1038/s41467-019-08878-82041-1723https://doaj.org/article/d30d0d8031994a8a983a53f2264b20ec2019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08878-8https://doaj.org/toc/2041-1723The halogen bond is well known for its ability to assemble supramolecules. Here, using NMR experiments, the authors reveal the role of these bonds in dynamic processes, finding that the halogen bond directly catalyzes dynamical rotation in solid cocrystals by reducing the associated energy barrier.Patrick M. J. SzellScott ZablotnyDavid L. BryceNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Patrick M. J. Szell Scott Zablotny David L. Bryce Halogen bonding as a supramolecular dynamics catalyst
description	The halogen bond is well known for its ability to assemble supramolecules. Here, using NMR experiments, the authors reveal the role of these bonds in dynamic processes, finding that the halogen bond directly catalyzes dynamical rotation in solid cocrystals by reducing the associated energy barrier.
format	article
author	Patrick M. J. Szell Scott Zablotny David L. Bryce
author_facet	Patrick M. J. Szell Scott Zablotny David L. Bryce
author_sort	Patrick M. J. Szell
title	Halogen bonding as a supramolecular dynamics catalyst
title_short	Halogen bonding as a supramolecular dynamics catalyst
title_full	Halogen bonding as a supramolecular dynamics catalyst
title_fullStr	Halogen bonding as a supramolecular dynamics catalyst
title_full_unstemmed	Halogen bonding as a supramolecular dynamics catalyst
title_sort	halogen bonding as a supramolecular dynamics catalyst
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/d30d0d8031994a8a983a53f2264b20ec
work_keys_str_mv	AT patrickmjszell halogenbondingasasupramoleculardynamicscatalyst AT scottzablotny halogenbondingasasupramoleculardynamicscatalyst AT davidlbryce halogenbondingasasupramoleculardynamicscatalyst
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Halogen bonding as a supramolecular dynamics catalyst

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