Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis

Catalytic amide bond-forming methods is important because they could potentially address the existing limitations of classical methods using superstoichiometric activating reagents. Here the authors show an Umpolung amidation reaction of carboxylic acids with nitroarenes and nitroalkanes enabled by...

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Autores principales:	Yunyun Ning, Shuaishuai Wang, Muzi Li, Jie Han, Chengjian Zhu, Jin Xie
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d3ce2c10fd0d492db89ee66b2fb0d294
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spelling	oai:doaj.org-article:d3ce2c10fd0d492db89ee66b2fb0d2942021-12-02T16:24:23ZSite-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis10.1038/s41467-021-24908-w2041-1723https://doaj.org/article/d3ce2c10fd0d492db89ee66b2fb0d2942021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24908-whttps://doaj.org/toc/2041-1723Catalytic amide bond-forming methods is important because they could potentially address the existing limitations of classical methods using superstoichiometric activating reagents. Here the authors show an Umpolung amidation reaction of carboxylic acids with nitroarenes and nitroalkanes enabled by FeI2, P(V)/P(III) and photoredox catalysis that avoids the production of byproducts.Yunyun NingShuaishuai WangMuzi LiJie HanChengjian ZhuJin XieNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yunyun Ning Shuaishuai Wang Muzi Li Jie Han Chengjian Zhu Jin Xie Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
description	Catalytic amide bond-forming methods is important because they could potentially address the existing limitations of classical methods using superstoichiometric activating reagents. Here the authors show an Umpolung amidation reaction of carboxylic acids with nitroarenes and nitroalkanes enabled by FeI2, P(V)/P(III) and photoredox catalysis that avoids the production of byproducts.
format	article
author	Yunyun Ning Shuaishuai Wang Muzi Li Jie Han Chengjian Zhu Jin Xie
author_facet	Yunyun Ning Shuaishuai Wang Muzi Li Jie Han Chengjian Zhu Jin Xie
author_sort	Yunyun Ning
title	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
title_short	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
title_full	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
title_fullStr	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
title_full_unstemmed	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis
title_sort	site-specific umpolung amidation of carboxylic acids via triplet synergistic catalysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d3ce2c10fd0d492db89ee66b2fb0d294
work_keys_str_mv	AT yunyunning sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis AT shuaishuaiwang sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis AT muzili sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis AT jiehan sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis AT chengjianzhu sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis AT jinxie sitespecificumpolungamidationofcarboxylicacidsviatripletsynergisticcatalysis
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Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis

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