A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface

A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface

Heterogeneous oxidation of bromide in atmospheric aqueous environments has long been suspected to be accelerated at the interface between aqueous solution and air. Here, the authors provide spectroscopic, kinetic and theoretical evidence for a rate limiting, surface active ozonide formed at the inte...

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Autores principales: Luca Artiglia, Jacinta Edebeli, Fabrizio Orlando, Shuzhen Chen, Ming-Tao Lee, Pablo Corral Arroyo, Anina Gilgen, Thorsten Bartels-Rausch, Armin Kleibert, Mario Vazdar, Marcelo Andres Carignano, Joseph S. Francisco, Paul B. Shepson, Ivan Gladich, Markus Ammann
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/d4264dc9afd84a6782f06ff8b576254e
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spelling oai:doaj.org-article:d4264dc9afd84a6782f06ff8b576254e2021-12-02T14:42:44ZA surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface10.1038/s41467-017-00823-x2041-1723https://doaj.org/article/d4264dc9afd84a6782f06ff8b576254e2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00823-xhttps://doaj.org/toc/2041-1723Heterogeneous oxidation of bromide in atmospheric aqueous environments has long been suspected to be accelerated at the interface between aqueous solution and air. Here, the authors provide spectroscopic, kinetic and theoretical evidence for a rate limiting, surface active ozonide formed at the interface.Luca ArtigliaJacinta EdebeliFabrizio OrlandoShuzhen ChenMing-Tao LeePablo Corral ArroyoAnina GilgenThorsten Bartels-RauschArmin KleibertMario VazdarMarcelo Andres CarignanoJoseph S. FranciscoPaul B. ShepsonIvan GladichMarkus AmmannNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Luca Artiglia
Jacinta Edebeli
Fabrizio Orlando
Shuzhen Chen
Ming-Tao Lee
Pablo Corral Arroyo
Anina Gilgen
Thorsten Bartels-Rausch
Armin Kleibert
Mario Vazdar
Marcelo Andres Carignano
Joseph S. Francisco
Paul B. Shepson
Ivan Gladich
Markus Ammann
A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
description Heterogeneous oxidation of bromide in atmospheric aqueous environments has long been suspected to be accelerated at the interface between aqueous solution and air. Here, the authors provide spectroscopic, kinetic and theoretical evidence for a rate limiting, surface active ozonide formed at the interface.
format article
author Luca Artiglia
Jacinta Edebeli
Fabrizio Orlando
Shuzhen Chen
Ming-Tao Lee
Pablo Corral Arroyo
Anina Gilgen
Thorsten Bartels-Rausch
Armin Kleibert
Mario Vazdar
Marcelo Andres Carignano
Joseph S. Francisco
Paul B. Shepson
Ivan Gladich
Markus Ammann
author_facet Luca Artiglia
Jacinta Edebeli
Fabrizio Orlando
Shuzhen Chen
Ming-Tao Lee
Pablo Corral Arroyo
Anina Gilgen
Thorsten Bartels-Rausch
Armin Kleibert
Mario Vazdar
Marcelo Andres Carignano
Joseph S. Francisco
Paul B. Shepson
Ivan Gladich
Markus Ammann
author_sort Luca Artiglia
title A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
title_short A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
title_full A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
title_fullStr A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
title_full_unstemmed A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
title_sort surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/d4264dc9afd84a6782f06ff8b576254e
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