Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks

Interactions between metal nanoparticles (NPs) and metal–organic frameworks (MOFs) in their composite forms have proven to exhibit beneficial properties. Here the authors present a unique approach to immobilise Pd NPs and, more importantly, to generate tunable basic sites within an anionic defective...

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Autores principales: Ying Chuan Tan, Hua Chun Zeng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/d4810cbf65d24d23a9635f34247b99bf
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spelling oai:doaj.org-article:d4810cbf65d24d23a9635f34247b99bf2021-12-02T17:31:30ZLewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks10.1038/s41467-018-06828-42041-1723https://doaj.org/article/d4810cbf65d24d23a9635f34247b99bf2018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06828-4https://doaj.org/toc/2041-1723Interactions between metal nanoparticles (NPs) and metal–organic frameworks (MOFs) in their composite forms have proven to exhibit beneficial properties. Here the authors present a unique approach to immobilise Pd NPs and, more importantly, to generate tunable basic sites within an anionic defective MOF.Ying Chuan TanHua Chun ZengNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Ying Chuan Tan
Hua Chun Zeng
Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
description Interactions between metal nanoparticles (NPs) and metal–organic frameworks (MOFs) in their composite forms have proven to exhibit beneficial properties. Here the authors present a unique approach to immobilise Pd NPs and, more importantly, to generate tunable basic sites within an anionic defective MOF.
format article
author Ying Chuan Tan
Hua Chun Zeng
author_facet Ying Chuan Tan
Hua Chun Zeng
author_sort Ying Chuan Tan
title Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
title_short Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
title_full Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
title_fullStr Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
title_full_unstemmed Lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
title_sort lewis basicity generated by localised charge imbalance in noble metal nanoparticle-embedded defective metal–organic frameworks
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/d4810cbf65d24d23a9635f34247b99bf
work_keys_str_mv AT yingchuantan lewisbasicitygeneratedbylocalisedchargeimbalanceinnoblemetalnanoparticleembeddeddefectivemetalorganicframeworks
AT huachunzeng lewisbasicitygeneratedbylocalisedchargeimbalanceinnoblemetalnanoparticleembeddeddefectivemetalorganicframeworks
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