Direct allylic C–H alkylation of enol silyl ethers enabled by photoredox–Brønsted base hybrid catalysis

Allylic C–H activation of enol silyl ethers via one-electron oxidation is usually accompanied by undesired desilylation. Here, under hybrid photoredox and Brønsted base catalysis, the authors show the mild functionalization of enol silyl ethers, providing a platform to access an array of complex car...

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Autores principales: Kohsuke Ohmatsu, Tsubasa Nakashima, Makoto Sato, Takashi Ooi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/d4b34167696a4514b3e6b9637c57d34e
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