From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond

Radicals of heavy main-group elements represent important intermediates in chemical synthesis, yet few have been isolated. Here the authors stabilize neutral stibinyl and bismuthinyl radicals using gallium-based ligands, and reduce the former to afford a Ga=Sb double bond-containing complex.

Guardado en:

Detalles Bibliográficos
Autores principales:	Chelladurai Ganesamoorthy, Christoph Helling, Christoph Wölper, Walter Frank, Eckhard Bill, George E. Cutsail, Stephan Schulz
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d5140502220e4a1cb90d07b971497c8f
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:d5140502220e4a1cb90d07b971497c8f
record_format	dspace
spelling	oai:doaj.org-article:d5140502220e4a1cb90d07b971497c8f2021-12-02T14:38:49ZFrom stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond10.1038/s41467-017-02581-22041-1723https://doaj.org/article/d5140502220e4a1cb90d07b971497c8f2018-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02581-2https://doaj.org/toc/2041-1723Radicals of heavy main-group elements represent important intermediates in chemical synthesis, yet few have been isolated. Here the authors stabilize neutral stibinyl and bismuthinyl radicals using gallium-based ligands, and reduce the former to afford a Ga=Sb double bond-containing complex.Chelladurai GanesamoorthyChristoph HellingChristoph WölperWalter FrankEckhard BillGeorge E. CutsailStephan SchulzNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chelladurai Ganesamoorthy Christoph Helling Christoph Wölper Walter Frank Eckhard Bill George E. Cutsail Stephan Schulz From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
description	Radicals of heavy main-group elements represent important intermediates in chemical synthesis, yet few have been isolated. Here the authors stabilize neutral stibinyl and bismuthinyl radicals using gallium-based ligands, and reduce the former to afford a Ga=Sb double bond-containing complex.
format	article
author	Chelladurai Ganesamoorthy Christoph Helling Christoph Wölper Walter Frank Eckhard Bill George E. Cutsail Stephan Schulz
author_facet	Chelladurai Ganesamoorthy Christoph Helling Christoph Wölper Walter Frank Eckhard Bill George E. Cutsail Stephan Schulz
author_sort	Chelladurai Ganesamoorthy
title	From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
title_short	From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
title_full	From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
title_fullStr	From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
title_full_unstemmed	From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
title_sort	from stable sb- and bi-centered radicals to a compound with a ga=sb double bond
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/d5140502220e4a1cb90d07b971497c8f
work_keys_str_mv	AT chelladuraiganesamoorthy fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT christophhelling fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT christophwolper fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT walterfrank fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT eckhardbill fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT georgeecutsail fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond AT stephanschulz fromstablesbandbicenteredradicalstoacompoundwithagasbdoublebond
_version_	1718390862472282112

From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond

Ejemplares similares