$Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis$
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Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis

The aim of the work was to synthesize new perspective compounds of palladium and platinum with nitrogenous bases (guanine), promising for use in biomedicine and catalysis. The article describes the synthesis of new [PdCl2(HGua)2]Cl2...

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Autores principales:	Anton Petrovich Novikov, Mikhail Alexandrovich Volkov, Alexey Vladimirovich Safonov, Mikhail Semenovich Grigoriev, Evgeny Vladilenovich Abkhalimov
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	X-ray diffraction analysis Hirshfeld surface analysis guanine palladium platinum metal-nitrogen bond Crystallography QD901-999
Acceso en línea:	https://doaj.org/article/d52870e83791417d879167c5cff1b772
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spelling	oai:doaj.org-article:d52870e83791417d879167c5cff1b7722021-11-25T17:19:36ZSynthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis10.3390/cryst111114172073-4352https://doaj.org/article/d52870e83791417d879167c5cff1b7722021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4352/11/11/1417https://doaj.org/toc/2073-4352The aim of the work was to synthesize new perspective compounds of palladium and platinum with nitrogenous bases (guanine), promising for use in biomedicine and catalysis. The article describes the synthesis of new [PdCl<sub>2</sub>(HGua)<sub>2</sub>]Cl<sub>2</sub>·H<sub>2</sub>O and [PtCl<sub>5</sub>(HGua)]·2H<sub>2</sub>O compounds using wet chemistry methods. The structure of the obtained single crystals was established by the method of single crystal X-ray diffraction. The complexes have an M-N bond, and the organic ligand is included in the first coordination sphere. The analysis of Hirshfeld surfaces for the obtained complexes and their analogues for the analysis of intermolecular interactions was carried out. In the palladium complex we obtained, π-halogen and π-stacking interactions were found; in analogues, such interactions were not found. π-halogen and halogen interactions were found in structure of platinum complex and its analogues.Anton Petrovich NovikovMikhail Alexandrovich VolkovAlexey Vladimirovich SafonovMikhail Semenovich GrigorievEvgeny Vladilenovich AbkhalimovMDPI AGarticleX-ray diffraction analysisHirshfeld surface analysisguaninepalladiumplatinummetal-nitrogen bondCrystallographyQD901-999ENCrystals, Vol 11, Iss 1417, p 1417 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	X-ray diffraction analysis Hirshfeld surface analysis guanine palladium platinum metal-nitrogen bond Crystallography QD901-999
spellingShingle	X-ray diffraction analysis Hirshfeld surface analysis guanine palladium platinum metal-nitrogen bond Crystallography QD901-999 Anton Petrovich Novikov Mikhail Alexandrovich Volkov Alexey Vladimirovich Safonov Mikhail Semenovich Grigoriev Evgeny Vladilenovich Abkhalimov Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
description	The aim of the work was to synthesize new perspective compounds of palladium and platinum with nitrogenous bases (guanine), promising for use in biomedicine and catalysis. The article describes the synthesis of new [PdCl<sub>2</sub>(HGua)<sub>2</sub>]Cl<sub>2</sub>·H<sub>2</sub>O and [PtCl<sub>5</sub>(HGua)]·2H<sub>2</sub>O compounds using wet chemistry methods. The structure of the obtained single crystals was established by the method of single crystal X-ray diffraction. The complexes have an M-N bond, and the organic ligand is included in the first coordination sphere. The analysis of Hirshfeld surfaces for the obtained complexes and their analogues for the analysis of intermolecular interactions was carried out. In the palladium complex we obtained, π-halogen and π-stacking interactions were found; in analogues, such interactions were not found. π-halogen and halogen interactions were found in structure of platinum complex and its analogues.
format	article
author	Anton Petrovich Novikov Mikhail Alexandrovich Volkov Alexey Vladimirovich Safonov Mikhail Semenovich Grigoriev Evgeny Vladilenovich Abkhalimov
author_facet	Anton Petrovich Novikov Mikhail Alexandrovich Volkov Alexey Vladimirovich Safonov Mikhail Semenovich Grigoriev Evgeny Vladilenovich Abkhalimov
author_sort	Anton Petrovich Novikov
title	Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
title_short	Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
title_full	Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
title_fullStr	Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
title_full_unstemmed	Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis
title_sort	synthesis and characterization of new guanine complexes of pt(iv) and pd(ii) by x-ray diffraction and hirshfeld surface analysis
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/d52870e83791417d879167c5cff1b772
work_keys_str_mv	AT antonpetrovichnovikov synthesisandcharacterizationofnewguaninecomplexesofptivandpdiibyxraydiffractionandhirshfeldsurfaceanalysis AT mikhailalexandrovichvolkov synthesisandcharacterizationofnewguaninecomplexesofptivandpdiibyxraydiffractionandhirshfeldsurfaceanalysis AT alexeyvladimirovichsafonov synthesisandcharacterizationofnewguaninecomplexesofptivandpdiibyxraydiffractionandhirshfeldsurfaceanalysis AT mikhailsemenovichgrigoriev synthesisandcharacterizationofnewguaninecomplexesofptivandpdiibyxraydiffractionandhirshfeldsurfaceanalysis AT evgenyvladilenovichabkhalimov synthesisandcharacterizationofnewguaninecomplexesofptivandpdiibyxraydiffractionandhirshfeldsurfaceanalysis
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Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis

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