Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

Abstract The contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, re...

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Autores principales:	Jacek Malinowski, Dagmara Jacewicz, Artur Sikorski, Mariusz Urbaniak, Przemysław Rybiński, Patrycja Parnicka, Adriana Zaleska-Medynska, Barbara Gawdzik, Joanna Drzeżdżon
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/d62583a688ab40698803a20a521869d4
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spelling	oai:doaj.org-article:d62583a688ab40698803a20a521869d42021-12-02T16:06:41ZCat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations10.1038/s41598-021-94056-02045-2322https://doaj.org/article/d62583a688ab40698803a20a521869d42021-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-94056-0https://doaj.org/toc/2045-2322Abstract The contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, requirement of high pressure or instability at high temperatures. In this paper, we present a new catalyst i.e. the crystalline complex compound possesing high catalytic activity in the oligomerization of olefins, such as 2-chloro-2-propen-1-ol and ethylene under very mild conditions (room temperature, 0.12 bar for ethylene oligomerization, atmospheric pressure for 2-chloro-2-propen-1-ol oligomerization). New material—Cat-CrNP ([nitrilotriacetato-1,10-phenanthroline]chromium(III) tetrahydrate) has been obtained as crystalline form of the nitrilotriacetate complex compound of chromium(III) with 1,10-phenanthroline and characterized in terms of its crystal structure by the XRD method and by multi-analytical investigations towards its physicochemical propeties The yield of catalytic oligomerization over Cat-CrNP reached to 213.92 g · mmol−1 · h−1· bar−1 and 3232 g · mmol−1 · h−1 · bar−1 for the 2-chloro-2-propen-1-ol and ethylene, respectively. Furthemore, the synthesis of Cat-CrNP is cheap, easy to perform and solvents used during preparation are environmentally friendly.Jacek MalinowskiDagmara JacewiczArtur SikorskiMariusz UrbaniakPrzemysław RybińskiPatrycja ParnickaAdriana Zaleska-MedynskaBarbara GawdzikJoanna DrzeżdżonNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Jacek Malinowski Dagmara Jacewicz Artur Sikorski Mariusz Urbaniak Przemysław Rybiński Patrycja Parnicka Adriana Zaleska-Medynska Barbara Gawdzik Joanna Drzeżdżon Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
description	Abstract The contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, requirement of high pressure or instability at high temperatures. In this paper, we present a new catalyst i.e. the crystalline complex compound possesing high catalytic activity in the oligomerization of olefins, such as 2-chloro-2-propen-1-ol and ethylene under very mild conditions (room temperature, 0.12 bar for ethylene oligomerization, atmospheric pressure for 2-chloro-2-propen-1-ol oligomerization). New material—Cat-CrNP ([nitrilotriacetato-1,10-phenanthroline]chromium(III) tetrahydrate) has been obtained as crystalline form of the nitrilotriacetate complex compound of chromium(III) with 1,10-phenanthroline and characterized in terms of its crystal structure by the XRD method and by multi-analytical investigations towards its physicochemical propeties The yield of catalytic oligomerization over Cat-CrNP reached to 213.92 g · mmol−1 · h−1· bar−1 and 3232 g · mmol−1 · h−1 · bar−1 for the 2-chloro-2-propen-1-ol and ethylene, respectively. Furthemore, the synthesis of Cat-CrNP is cheap, easy to perform and solvents used during preparation are environmentally friendly.
format	article
author	Jacek Malinowski Dagmara Jacewicz Artur Sikorski Mariusz Urbaniak Przemysław Rybiński Patrycja Parnicka Adriana Zaleska-Medynska Barbara Gawdzik Joanna Drzeżdżon
author_facet	Jacek Malinowski Dagmara Jacewicz Artur Sikorski Mariusz Urbaniak Przemysław Rybiński Patrycja Parnicka Adriana Zaleska-Medynska Barbara Gawdzik Joanna Drzeżdżon
author_sort	Jacek Malinowski
title	Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
title_short	Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
title_full	Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
title_fullStr	Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
title_full_unstemmed	Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
title_sort	cat-crnp as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d62583a688ab40698803a20a521869d4
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Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

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