Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions

In order to explore effect of structure on the temperature sensitivity of partially carbonized carbon fibers, different heat treatment temperatures (700, 750 and 800 °C) and heat treatment times (3 and 9 min) were used to prepare fibers with different structures. The electrical resistivities were mo...

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Autores principales: Zijin Liu, Jun Wang, Chang Li, Cheng Zheng, Bin Zhang
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:d672138fe12a4002b6b137ddb0fc7bf62021-11-25T18:16:13ZRemarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions10.3390/ma142270851996-1944https://doaj.org/article/d672138fe12a4002b6b137ddb0fc7bf62021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/7085https://doaj.org/toc/1996-1944In order to explore effect of structure on the temperature sensitivity of partially carbonized carbon fibers, different heat treatment temperatures (700, 750 and 800 °C) and heat treatment times (3 and 9 min) were used to prepare fibers with different structures. The electrical resistivities were monitored whilst the room temperature was increased from 30 to 100 °C, which was used to characterize the temperature sensitivity. The fibers showed negative temperature coefficients in the temperature range. Infrared spectra, an element analysis, a scanning electron microscope (SEM), Raman spectroscopy and X-ray diffraction measurements were used to study the microstructure of the fibers. Through the analysis, the proportions of the graphite-like structure, graphitization degree and size of the graphite-like structure crystallite influenced the temperature sensitivity. The main electron transfer method used for the fibers was variable-range hopping. This indicated that the fibers had a potential application of preparing thermistors in polymer composites.Zijin LiuJun WangChang LiCheng ZhengBin ZhangMDPI AGarticlecarbon fiberstemperature sensitivitygraphitized-like structureconductive mechanismTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 7085, p 7085 (2021)
institution DOAJ
collection DOAJ
language EN
topic carbon fibers
temperature sensitivity
graphitized-like structure
conductive mechanism
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle carbon fibers
temperature sensitivity
graphitized-like structure
conductive mechanism
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Zijin Liu
Jun Wang
Chang Li
Cheng Zheng
Bin Zhang
Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
description In order to explore effect of structure on the temperature sensitivity of partially carbonized carbon fibers, different heat treatment temperatures (700, 750 and 800 °C) and heat treatment times (3 and 9 min) were used to prepare fibers with different structures. The electrical resistivities were monitored whilst the room temperature was increased from 30 to 100 °C, which was used to characterize the temperature sensitivity. The fibers showed negative temperature coefficients in the temperature range. Infrared spectra, an element analysis, a scanning electron microscope (SEM), Raman spectroscopy and X-ray diffraction measurements were used to study the microstructure of the fibers. Through the analysis, the proportions of the graphite-like structure, graphitization degree and size of the graphite-like structure crystallite influenced the temperature sensitivity. The main electron transfer method used for the fibers was variable-range hopping. This indicated that the fibers had a potential application of preparing thermistors in polymer composites.
format article
author Zijin Liu
Jun Wang
Chang Li
Cheng Zheng
Bin Zhang
author_facet Zijin Liu
Jun Wang
Chang Li
Cheng Zheng
Bin Zhang
author_sort Zijin Liu
title Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
title_short Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
title_full Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
title_fullStr Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
title_full_unstemmed Remarkable Temperature Sensitivity of Partially Carbonized Carbon Fibers with Different Microstructures and Compositions
title_sort remarkable temperature sensitivity of partially carbonized carbon fibers with different microstructures and compositions
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/d672138fe12a4002b6b137ddb0fc7bf6
work_keys_str_mv AT zijinliu remarkabletemperaturesensitivityofpartiallycarbonizedcarbonfiberswithdifferentmicrostructuresandcompositions
AT junwang remarkabletemperaturesensitivityofpartiallycarbonizedcarbonfiberswithdifferentmicrostructuresandcompositions
AT changli remarkabletemperaturesensitivityofpartiallycarbonizedcarbonfiberswithdifferentmicrostructuresandcompositions
AT chengzheng remarkabletemperaturesensitivityofpartiallycarbonizedcarbonfiberswithdifferentmicrostructuresandcompositions
AT binzhang remarkabletemperaturesensitivityofpartiallycarbonizedcarbonfiberswithdifferentmicrostructuresandcompositions
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