Directing isomerization reactions of cumulenes with electric fields

Electric fields have been proposed as having a distinct ability to catalyse chemical reactions through stabilizing polar intermediates. Here, the authors show that electric fields can catalyse the cis-to-trans isomerization reactions of cumulenes in solution in a scanning tunnelling microscope

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Autores principales: Yaping Zang, Qi Zou, Tianren Fu, Fay Ng, Brandon Fowler, Jingjing Yang, Hexing Li, Michael L. Steigerwald, Colin Nuckolls, Latha Venkataraman
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/d7445b4e7e7244b888245d1ac81a4373
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spelling oai:doaj.org-article:d7445b4e7e7244b888245d1ac81a43732021-12-02T14:39:58ZDirecting isomerization reactions of cumulenes with electric fields10.1038/s41467-019-12487-w2041-1723https://doaj.org/article/d7445b4e7e7244b888245d1ac81a43732019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12487-whttps://doaj.org/toc/2041-1723Electric fields have been proposed as having a distinct ability to catalyse chemical reactions through stabilizing polar intermediates. Here, the authors show that electric fields can catalyse the cis-to-trans isomerization reactions of cumulenes in solution in a scanning tunnelling microscopeYaping ZangQi ZouTianren FuFay NgBrandon FowlerJingjing YangHexing LiMichael L. SteigerwaldColin NuckollsLatha VenkataramanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yaping Zang
Qi Zou
Tianren Fu
Fay Ng
Brandon Fowler
Jingjing Yang
Hexing Li
Michael L. Steigerwald
Colin Nuckolls
Latha Venkataraman
Directing isomerization reactions of cumulenes with electric fields
description Electric fields have been proposed as having a distinct ability to catalyse chemical reactions through stabilizing polar intermediates. Here, the authors show that electric fields can catalyse the cis-to-trans isomerization reactions of cumulenes in solution in a scanning tunnelling microscope
format article
author Yaping Zang
Qi Zou
Tianren Fu
Fay Ng
Brandon Fowler
Jingjing Yang
Hexing Li
Michael L. Steigerwald
Colin Nuckolls
Latha Venkataraman
author_facet Yaping Zang
Qi Zou
Tianren Fu
Fay Ng
Brandon Fowler
Jingjing Yang
Hexing Li
Michael L. Steigerwald
Colin Nuckolls
Latha Venkataraman
author_sort Yaping Zang
title Directing isomerization reactions of cumulenes with electric fields
title_short Directing isomerization reactions of cumulenes with electric fields
title_full Directing isomerization reactions of cumulenes with electric fields
title_fullStr Directing isomerization reactions of cumulenes with electric fields
title_full_unstemmed Directing isomerization reactions of cumulenes with electric fields
title_sort directing isomerization reactions of cumulenes with electric fields
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/d7445b4e7e7244b888245d1ac81a4373
work_keys_str_mv AT yapingzang directingisomerizationreactionsofcumuleneswithelectricfields
AT qizou directingisomerizationreactionsofcumuleneswithelectricfields
AT tianrenfu directingisomerizationreactionsofcumuleneswithelectricfields
AT fayng directingisomerizationreactionsofcumuleneswithelectricfields
AT brandonfowler directingisomerizationreactionsofcumuleneswithelectricfields
AT jingjingyang directingisomerizationreactionsofcumuleneswithelectricfields
AT hexingli directingisomerizationreactionsofcumuleneswithelectricfields
AT michaellsteigerwald directingisomerizationreactionsofcumuleneswithelectricfields
AT colinnuckolls directingisomerizationreactionsofcumuleneswithelectricfields
AT lathavenkataraman directingisomerizationreactionsofcumuleneswithelectricfields
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