Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst

Homogeneous earth-abundant metal catalysis based on well-defined metal complexes is of interest for organic synthesis, but typically employs expensive catalysts, air sensitive or synthetically challenging chemicals. Here, the authors report an efficient and regio-selective catalytic system for hydro...

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Autores principales:	Chuhan Li, Shuo Song, Yuling Li, Chang Xu, Qiquan Luo, Yinlong Guo, Xiaoming Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d7e2f420c49940838e61784d862c213f
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spelling	oai:doaj.org-article:d7e2f420c49940838e61784d862c213f2021-12-02T17:12:20ZSelective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst10.1038/s41467-021-24117-52041-1723https://doaj.org/article/d7e2f420c49940838e61784d862c213f2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24117-5https://doaj.org/toc/2041-1723Homogeneous earth-abundant metal catalysis based on well-defined metal complexes is of interest for organic synthesis, but typically employs expensive catalysts, air sensitive or synthetically challenging chemicals. Here, the authors report an efficient and regio-selective catalytic system for hydroboration of vinylarenes and organic nitriles with HBPin, using commercially available CoI2 and KO t Bu under ligand-free conditions.Chuhan LiShuo SongYuling LiChang XuQiquan LuoYinlong GuoXiaoming WangNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chuhan Li Shuo Song Yuling Li Chang Xu Qiquan Luo Yinlong Guo Xiaoming Wang Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
description	Homogeneous earth-abundant metal catalysis based on well-defined metal complexes is of interest for organic synthesis, but typically employs expensive catalysts, air sensitive or synthetically challenging chemicals. Here, the authors report an efficient and regio-selective catalytic system for hydroboration of vinylarenes and organic nitriles with HBPin, using commercially available CoI2 and KO t Bu under ligand-free conditions.
format	article
author	Chuhan Li Shuo Song Yuling Li Chang Xu Qiquan Luo Yinlong Guo Xiaoming Wang
author_facet	Chuhan Li Shuo Song Yuling Li Chang Xu Qiquan Luo Yinlong Guo Xiaoming Wang
author_sort	Chuhan Li
title	Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
title_short	Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
title_full	Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
title_fullStr	Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
title_full_unstemmed	Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
title_sort	selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d7e2f420c49940838e61784d862c213f
work_keys_str_mv	AT chuhanli selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT shuosong selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT yulingli selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT changxu selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT qiquanluo selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT yinlongguo selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst AT xiaomingwang selectivehydroborationofunsaturatedbondsbyaneasilyaccessibleheterotopiccobaltcatalyst
_version_	1718381464542773248

Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst

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