Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates

Abstract Facile, effective and reliable etching technique for the formation of uniform silicon (Si) nanowire arrays were realized through the incorporation of back substrates with metal-assisted chemical etching (MaCE). In comparison with conventional MaCE process, a dramatic increase of etching rat...

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Autores principales: Chia-Yun Chen, Ta-Cheng Wei, Cheng-Ting Lin, Jheng-Yi Li
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/d7f21b0c614b449ba0ee50acf0d1507d
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spelling oai:doaj.org-article:d7f21b0c614b449ba0ee50acf0d1507d2021-12-02T12:32:13ZEnhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates10.1038/s41598-017-03498-y2045-2322https://doaj.org/article/d7f21b0c614b449ba0ee50acf0d1507d2017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-03498-yhttps://doaj.org/toc/2045-2322Abstract Facile, effective and reliable etching technique for the formation of uniform silicon (Si) nanowire arrays were realized through the incorporation of back substrates with metal-assisted chemical etching (MaCE). In comparison with conventional MaCE process, a dramatic increase of etching rates upon MaCE process could be found by employing the conductive back substrates on p-type Si, while additionally prevented the creation of nanopores from catalytic etching reaction. Examinations on the involving etching kinetics, morphologies, wetting behaviors and surface structures were performed that validated the role of back substrates upon MaCE process. It was found that the involved two pathways for the extraction of electrons within Si favored the localized oxidation of Si at Si/Ag interfaces, thereby increasing the etching rate of MaCE process. This back-substrate involved MaCE could potentially meet the practical needs for the high-yield formation of Si nanowire arrays.Chia-Yun ChenTa-Cheng WeiCheng-Ting LinJheng-Yi LiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Chia-Yun Chen
Ta-Cheng Wei
Cheng-Ting Lin
Jheng-Yi Li
Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
description Abstract Facile, effective and reliable etching technique for the formation of uniform silicon (Si) nanowire arrays were realized through the incorporation of back substrates with metal-assisted chemical etching (MaCE). In comparison with conventional MaCE process, a dramatic increase of etching rates upon MaCE process could be found by employing the conductive back substrates on p-type Si, while additionally prevented the creation of nanopores from catalytic etching reaction. Examinations on the involving etching kinetics, morphologies, wetting behaviors and surface structures were performed that validated the role of back substrates upon MaCE process. It was found that the involved two pathways for the extraction of electrons within Si favored the localized oxidation of Si at Si/Ag interfaces, thereby increasing the etching rate of MaCE process. This back-substrate involved MaCE could potentially meet the practical needs for the high-yield formation of Si nanowire arrays.
format article
author Chia-Yun Chen
Ta-Cheng Wei
Cheng-Ting Lin
Jheng-Yi Li
author_facet Chia-Yun Chen
Ta-Cheng Wei
Cheng-Ting Lin
Jheng-Yi Li
author_sort Chia-Yun Chen
title Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
title_short Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
title_full Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
title_fullStr Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
title_full_unstemmed Enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
title_sort enhancing formation rate of highly-oriented silicon nanowire arrays with the assistance of back substrates
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/d7f21b0c614b449ba0ee50acf0d1507d
work_keys_str_mv AT chiayunchen enhancingformationrateofhighlyorientedsiliconnanowirearrayswiththeassistanceofbacksubstrates
AT tachengwei enhancingformationrateofhighlyorientedsiliconnanowirearrayswiththeassistanceofbacksubstrates
AT chengtinglin enhancingformationrateofhighlyorientedsiliconnanowirearrayswiththeassistanceofbacksubstrates
AT jhengyili enhancingformationrateofhighlyorientedsiliconnanowirearrayswiththeassistanceofbacksubstrates
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