Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman

General and stereoselective synthesis of tetracyclic isochroman-containing polyketide oligomers is challenging. Here, the authors report on an Au(I)/chiral Sc(III) bimetallic catalyst for a biomimetic asymmetric hetero-Diels–Alder reaction for in-situ generation of isochromene and ortho-quinonemethi...

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Autores principales:	Xiangfeng Lin, Xianghui Liu, Kai Wang, Qian Li, Yan Liu, Can Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d8067b9568c34fa380fcc342497aa73e
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spelling	oai:doaj.org-article:d8067b9568c34fa380fcc342497aa73e2021-12-02T15:10:51ZBiomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman10.1038/s41467-021-25198-y2041-1723https://doaj.org/article/d8067b9568c34fa380fcc342497aa73e2021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25198-yhttps://doaj.org/toc/2041-1723General and stereoselective synthesis of tetracyclic isochroman-containing polyketide oligomers is challenging. Here, the authors report on an Au(I)/chiral Sc(III) bimetallic catalyst for a biomimetic asymmetric hetero-Diels–Alder reaction for in-situ generation of isochromene and ortho-quinonemethide.Xiangfeng LinXianghui LiuKai WangQian LiYan LiuCan LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiangfeng Lin Xianghui Liu Kai Wang Qian Li Yan Liu Can Li Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
description	General and stereoselective synthesis of tetracyclic isochroman-containing polyketide oligomers is challenging. Here, the authors report on an Au(I)/chiral Sc(III) bimetallic catalyst for a biomimetic asymmetric hetero-Diels–Alder reaction for in-situ generation of isochromene and ortho-quinonemethide.
format	article
author	Xiangfeng Lin Xianghui Liu Kai Wang Qian Li Yan Liu Can Li
author_facet	Xiangfeng Lin Xianghui Liu Kai Wang Qian Li Yan Liu Can Li
author_sort	Xiangfeng Lin
title	Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
title_short	Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
title_full	Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
title_fullStr	Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
title_full_unstemmed	Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
title_sort	biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d8067b9568c34fa380fcc342497aa73e
work_keys_str_mv	AT xiangfenglin biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman AT xianghuiliu biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman AT kaiwang biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman AT qianli biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman AT yanliu biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman AT canli biomimeticapproachtothecatalyticenantioselectivesynthesisoftetracyclicisochroman
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Biomimetic approach to the catalytic enantioselective synthesis of tetracyclic isochroman

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