Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder

Geopolymer binders are adjudged as the latest wave of sustainable alkali-activated materials for soil stabilization due to their excellent bonding properties. This study applied metakaolin as a precursor for synthesizing the geopolymer binder by employing the mixture of quicklime and sodium bicarbon...

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Autores principales: Shengnian Wang, Jun Su, Zhijian Wu, Wei Ma, Yue Li, Honglei Hui
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Lenguaje:EN
Publicado: Frontiers Media S.A. 2021
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Acceso en línea:https://doaj.org/article/d857e4086bc444fbad29bcbfe9298a4a
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spelling oai:doaj.org-article:d857e4086bc444fbad29bcbfe9298a4a2021-12-01T05:03:17ZSilty Clay Stabilization Using Metakaolin-Based Geopolymer Binder2296-424X10.3389/fphy.2021.769786https://doaj.org/article/d857e4086bc444fbad29bcbfe9298a4a2021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fphy.2021.769786/fullhttps://doaj.org/toc/2296-424XGeopolymer binders are adjudged as the latest wave of sustainable alkali-activated materials for soil stabilization due to their excellent bonding properties. This study applied metakaolin as a precursor for synthesizing the geopolymer binder by employing the mixture of quicklime and sodium bicarbonate as an alkali activator. The optimal mass mixing ratio of the alkali activator, metakaolin, and silty clay was determined by unconfined compression tests. The stabilization mechanisms of the geopolymer binder were measured by x-ray diffraction and Fourier transform infrared spectroscopy. The microstructural characteristics of the geopolymer-stabilized silty clay were observed by scanning electron microscopy with an energy dispersive x-ray spectroscopy and mercury intrusion porosimetry test for understanding the strengthening mechanism of the silty clay after the treatment. Results indicate that the optimal mass mixing ratio of the alkali activator, metakaolin, and silty clay is 1:2:17, and the unconfined compressive strength of the geopolymer-stabilized silty clay reaches the maximum value of 0.85 MPa with adding 15 wt% of the geopolymer binder. Diffraction patterns show an insufficient polymerization of the geopolymer binder in the silty clay in the early days but a rapid synthesis of aluminosilicate gels after that. The new asymmetrical stretching vibration peaks signified the formation of aluminosilicate networks and are responsible for the strength improvement of the silty clay. Microstructural analyses further confirm the formation of aluminosilicate gels and their positive impacts on the structure of the silty clay over curing age.Shengnian WangJun SuZhijian WuWei MaYue LiHonglei HuiFrontiers Media S.A.articlesoil stabilizationgeopolymeralkali-activationmixing ratiomicrostructural characteristicsPhysicsQC1-999ENFrontiers in Physics, Vol 9 (2021)
institution DOAJ
collection DOAJ
language EN
topic soil stabilization
geopolymer
alkali-activation
mixing ratio
microstructural characteristics
Physics
QC1-999
spellingShingle soil stabilization
geopolymer
alkali-activation
mixing ratio
microstructural characteristics
Physics
QC1-999
Shengnian Wang
Jun Su
Zhijian Wu
Wei Ma
Yue Li
Honglei Hui
Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
description Geopolymer binders are adjudged as the latest wave of sustainable alkali-activated materials for soil stabilization due to their excellent bonding properties. This study applied metakaolin as a precursor for synthesizing the geopolymer binder by employing the mixture of quicklime and sodium bicarbonate as an alkali activator. The optimal mass mixing ratio of the alkali activator, metakaolin, and silty clay was determined by unconfined compression tests. The stabilization mechanisms of the geopolymer binder were measured by x-ray diffraction and Fourier transform infrared spectroscopy. The microstructural characteristics of the geopolymer-stabilized silty clay were observed by scanning electron microscopy with an energy dispersive x-ray spectroscopy and mercury intrusion porosimetry test for understanding the strengthening mechanism of the silty clay after the treatment. Results indicate that the optimal mass mixing ratio of the alkali activator, metakaolin, and silty clay is 1:2:17, and the unconfined compressive strength of the geopolymer-stabilized silty clay reaches the maximum value of 0.85 MPa with adding 15 wt% of the geopolymer binder. Diffraction patterns show an insufficient polymerization of the geopolymer binder in the silty clay in the early days but a rapid synthesis of aluminosilicate gels after that. The new asymmetrical stretching vibration peaks signified the formation of aluminosilicate networks and are responsible for the strength improvement of the silty clay. Microstructural analyses further confirm the formation of aluminosilicate gels and their positive impacts on the structure of the silty clay over curing age.
format article
author Shengnian Wang
Jun Su
Zhijian Wu
Wei Ma
Yue Li
Honglei Hui
author_facet Shengnian Wang
Jun Su
Zhijian Wu
Wei Ma
Yue Li
Honglei Hui
author_sort Shengnian Wang
title Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
title_short Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
title_full Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
title_fullStr Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
title_full_unstemmed Silty Clay Stabilization Using Metakaolin-Based Geopolymer Binder
title_sort silty clay stabilization using metakaolin-based geopolymer binder
publisher Frontiers Media S.A.
publishDate 2021
url https://doaj.org/article/d857e4086bc444fbad29bcbfe9298a4a
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AT zhijianwu siltyclaystabilizationusingmetakaolinbasedgeopolymerbinder
AT weima siltyclaystabilizationusingmetakaolinbasedgeopolymerbinder
AT yueli siltyclaystabilizationusingmetakaolinbasedgeopolymerbinder
AT hongleihui siltyclaystabilizationusingmetakaolinbasedgeopolymerbinder
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