Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp

In this paper, the effect of D0 temperature, Kappa factor and the final pH value on bleaching sulfate bleached pine wood pulp was studied. The results showed that the bleaching efficiency was better when the pH value was 4, and the amount of absorbable organic halogen (AOX) in the bleaching wastewat...

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Autores principales: Lijie Huang, Zhehao Wei, Yanan Wang, Xiaoxue Han, Haobin Chen, Chongxing Huang, Yingnan Wei
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Publicado: AIP Publishing LLC 2021
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spelling oai:doaj.org-article:d89e15fd369f45fea541f94b14d6436e2021-12-01T18:52:06ZEffect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp2158-322610.1063/5.0064470https://doaj.org/article/d89e15fd369f45fea541f94b14d6436e2021-11-01T00:00:00Zhttp://dx.doi.org/10.1063/5.0064470https://doaj.org/toc/2158-3226In this paper, the effect of D0 temperature, Kappa factor and the final pH value on bleaching sulfate bleached pine wood pulp was studied. The results showed that the bleaching efficiency was better when the pH value was 4, and the amount of absorbable organic halogen (AOX) in the bleaching wastewater was decreased. The Kappa factor is linear with the whiteness in the range of 0–0.15. With the increase of the Kappa factor, the amount of AOX in bleaching wastewater of D0 and Ep gradually increases. High temperature bleaching can reduce AOX production, but some fibers are hydrolyzed, leading to a decrease in pulp viscosity. The effects of chlorine dioxide solution adding sodium dihydrogen phosphate (NaH2PO4) and dimethylsulfoxide (DMSO) on pulp bleaching were investigated. The results showed that both solutions could reduce the amount of AOX in bleaching wastewater. Among them, the addition of NaH2PO4 in chlorine dioxide increased pulp whiteness, while the addition of DMSO was the opposite. Scanning electron microscope showed that a small amount of hollow cracks and more voids appeared on the surface of pulp fibers after the addition of NaH2PO4. Pulp fibers bleached by the chlorine dioxide adding DMSO have more folds and less voids on the surface. The surface wrinkles of pulp fibers increased with the addition of DMSO and the voids were less. FT-IR showed that the number of chromophore groups in the pulp bleached by chlorine dioxide adding NaH2PO4 were decreased. However, the lignin characteristic absorption peak in the pulp bleached by chlorine dioxide adding DMSO increased at the intensity of 1062 and 1160 cm−1, which indicated that there were more residual chromophore groups.Lijie HuangZhehao WeiYanan WangXiaoxue HanHaobin ChenChongxing HuangYingnan WeiAIP Publishing LLCarticlePhysicsQC1-999ENAIP Advances, Vol 11, Iss 11, Pp 115224-115224-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
spellingShingle Physics
QC1-999
Lijie Huang
Zhehao Wei
Yanan Wang
Xiaoxue Han
Haobin Chen
Chongxing Huang
Yingnan Wei
Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
description In this paper, the effect of D0 temperature, Kappa factor and the final pH value on bleaching sulfate bleached pine wood pulp was studied. The results showed that the bleaching efficiency was better when the pH value was 4, and the amount of absorbable organic halogen (AOX) in the bleaching wastewater was decreased. The Kappa factor is linear with the whiteness in the range of 0–0.15. With the increase of the Kappa factor, the amount of AOX in bleaching wastewater of D0 and Ep gradually increases. High temperature bleaching can reduce AOX production, but some fibers are hydrolyzed, leading to a decrease in pulp viscosity. The effects of chlorine dioxide solution adding sodium dihydrogen phosphate (NaH2PO4) and dimethylsulfoxide (DMSO) on pulp bleaching were investigated. The results showed that both solutions could reduce the amount of AOX in bleaching wastewater. Among them, the addition of NaH2PO4 in chlorine dioxide increased pulp whiteness, while the addition of DMSO was the opposite. Scanning electron microscope showed that a small amount of hollow cracks and more voids appeared on the surface of pulp fibers after the addition of NaH2PO4. Pulp fibers bleached by the chlorine dioxide adding DMSO have more folds and less voids on the surface. The surface wrinkles of pulp fibers increased with the addition of DMSO and the voids were less. FT-IR showed that the number of chromophore groups in the pulp bleached by chlorine dioxide adding NaH2PO4 were decreased. However, the lignin characteristic absorption peak in the pulp bleached by chlorine dioxide adding DMSO increased at the intensity of 1062 and 1160 cm−1, which indicated that there were more residual chromophore groups.
format article
author Lijie Huang
Zhehao Wei
Yanan Wang
Xiaoxue Han
Haobin Chen
Chongxing Huang
Yingnan Wei
author_facet Lijie Huang
Zhehao Wei
Yanan Wang
Xiaoxue Han
Haobin Chen
Chongxing Huang
Yingnan Wei
author_sort Lijie Huang
title Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
title_short Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
title_full Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
title_fullStr Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
title_full_unstemmed Effect of chlorine dioxide with NaH2PO4 and DMSO on bleaching of kraft pine pulp
title_sort effect of chlorine dioxide with nah2po4 and dmso on bleaching of kraft pine pulp
publisher AIP Publishing LLC
publishDate 2021
url https://doaj.org/article/d89e15fd369f45fea541f94b14d6436e
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