Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.
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| Autores principales: | , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2017
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/d8a3542ba4944c2a933d8921207793e4 |
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| Sumario: | Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant. |
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