Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition

Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.

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Autores principales:	Yoshihiro Sohtome, Genta Nakamura, Atsuya Muranaka, Daisuke Hashizume, Sylvain Lectard, Teruhisa Tsuchimoto, Masanobu Uchiyama, Mikiko Sodeoka
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d8a3542ba4944c2a933d8921207793e4
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spelling	oai:doaj.org-article:d8a3542ba4944c2a933d8921207793e42021-12-02T14:41:18ZNaked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition10.1038/ncomms148752041-1723https://doaj.org/article/d8a3542ba4944c2a933d8921207793e42017-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms14875https://doaj.org/toc/2041-1723Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.Yoshihiro SohtomeGenta NakamuraAtsuya MuranakaDaisuke HashizumeSylvain LectardTeruhisa TsuchimotoMasanobu UchiyamaMikiko SodeokaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yoshihiro Sohtome Genta Nakamura Atsuya Muranaka Daisuke Hashizume Sylvain Lectard Teruhisa Tsuchimoto Masanobu Uchiyama Mikiko Sodeoka Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
description	Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.
format	article
author	Yoshihiro Sohtome Genta Nakamura Atsuya Muranaka Daisuke Hashizume Sylvain Lectard Teruhisa Tsuchimoto Masanobu Uchiyama Mikiko Sodeoka
author_facet	Yoshihiro Sohtome Genta Nakamura Atsuya Muranaka Daisuke Hashizume Sylvain Lectard Teruhisa Tsuchimoto Masanobu Uchiyama Mikiko Sodeoka
author_sort	Yoshihiro Sohtome
title	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_short	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_full	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_fullStr	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_full_unstemmed	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_sort	naked d-orbital in a centrochiral ni(ii) complex as a catalyst for asymmetric [3+2] cycloaddition
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/d8a3542ba4944c2a933d8921207793e4
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Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition

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