The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector

Olive oil production using three-phase decanter systems creates olive oil and two by-products: olive mill wastewater (OMWW) and pomace. These by-products contain the highest share of polyphenolic compounds that are known to be associated with beneficial effects on human health. Therefore, they are a...

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Autores principales: Kelly Peeters, Ana Miklavčič Višnjevec, Esakkiammal Sudha Esakkimuthu, Matthew Schwarzkopf, Črtomir Tavzes
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:d8a906a114814094a1ccce5c7de997e92021-11-25T18:28:37ZThe Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector10.3390/molecules262269461420-3049https://doaj.org/article/d8a906a114814094a1ccce5c7de997e92021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6946https://doaj.org/toc/1420-3049Olive oil production using three-phase decanter systems creates olive oil and two by-products: olive mill wastewater (OMWW) and pomace. These by-products contain the highest share of polyphenolic compounds that are known to be associated with beneficial effects on human health. Therefore, they are an attractive source of phenolic compounds for further industrial use in the cosmetic, pharmaceutical and food industries. The use of these phenolics is limited due to difficulties in recovery, high reactivity, complexity of the OMWW matrix and different physiochemical properties of phenolic compounds. This research, focused on OMWW, was performed in two phases. First, different polyphenol extraction methods were compared to obtain the method that yields the highest polyphenol concentration. Twenty-five phenolic compounds and their isomers were determined. Acidifying OMWW, followed by five minutes of ultrasonication, resulted in the highest measured polyphenol content of 27 mg/L. Second, the collection of polyphenolic compounds from OMWW via adsorption on unmodified iron (II, III) oxide particles was investigated. Although low yields were obtained for removed polyphenolic compounds in one removal cycle, the process has a high capability to be repeated.Kelly PeetersAna Miklavčič VišnjevecEsakkiammal Sudha EsakkimuthuMatthew SchwarzkopfČrtomir TavzesMDPI AGarticlepolyphenolic compoundsolive mill wastewaterextraction techniquesFe<sub>3</sub>O<sub>4</sub> particlesmagnetic collectionadsorption and desorptionOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6946, p 6946 (2021)
institution DOAJ
collection DOAJ
language EN
topic polyphenolic compounds
olive mill wastewater
extraction techniques
Fe<sub>3</sub>O<sub>4</sub> particles
magnetic collection
adsorption and desorption
Organic chemistry
QD241-441
spellingShingle polyphenolic compounds
olive mill wastewater
extraction techniques
Fe<sub>3</sub>O<sub>4</sub> particles
magnetic collection
adsorption and desorption
Organic chemistry
QD241-441
Kelly Peeters
Ana Miklavčič Višnjevec
Esakkiammal Sudha Esakkimuthu
Matthew Schwarzkopf
Črtomir Tavzes
The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
description Olive oil production using three-phase decanter systems creates olive oil and two by-products: olive mill wastewater (OMWW) and pomace. These by-products contain the highest share of polyphenolic compounds that are known to be associated with beneficial effects on human health. Therefore, they are an attractive source of phenolic compounds for further industrial use in the cosmetic, pharmaceutical and food industries. The use of these phenolics is limited due to difficulties in recovery, high reactivity, complexity of the OMWW matrix and different physiochemical properties of phenolic compounds. This research, focused on OMWW, was performed in two phases. First, different polyphenol extraction methods were compared to obtain the method that yields the highest polyphenol concentration. Twenty-five phenolic compounds and their isomers were determined. Acidifying OMWW, followed by five minutes of ultrasonication, resulted in the highest measured polyphenol content of 27 mg/L. Second, the collection of polyphenolic compounds from OMWW via adsorption on unmodified iron (II, III) oxide particles was investigated. Although low yields were obtained for removed polyphenolic compounds in one removal cycle, the process has a high capability to be repeated.
format article
author Kelly Peeters
Ana Miklavčič Višnjevec
Esakkiammal Sudha Esakkimuthu
Matthew Schwarzkopf
Črtomir Tavzes
author_facet Kelly Peeters
Ana Miklavčič Višnjevec
Esakkiammal Sudha Esakkimuthu
Matthew Schwarzkopf
Črtomir Tavzes
author_sort Kelly Peeters
title The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
title_short The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
title_full The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
title_fullStr The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
title_full_unstemmed The Valorisation of Olive Mill Wastewater from Slovenian Istria by Fe<sub>3</sub>O<sub>4</sub> Particles to Recover Polyphenolic Compounds for the Chemical Specialties Sector
title_sort valorisation of olive mill wastewater from slovenian istria by fe<sub>3</sub>o<sub>4</sub> particles to recover polyphenolic compounds for the chemical specialties sector
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/d8a906a114814094a1ccce5c7de997e9
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