Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/d9671dfd9f124e13884e329a3f5ad3b2 |
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| Sumario: | High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions. |
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